高分子保护的铂系金属簇的制备、表征及对间苯氧基苯甲醛催化-物理化学专业论文.docxVIP

·‘髑65282高分子保护的铂系金属簇的制各、表征及对间苯氧基苯甲醛催化 ·‘髑65282 高分子保护的铂系金属簇的制各、表征及对间苯氧基苯甲醛催化 中文摘要 摘要 f1)用乙醇还原的方法制各了PVP保护的铂纳米金属簇。并应用TEM、UV-VIS对铂 金属簇进行了表征。研究了常压下PVP／Pt催化间苯氧基苯甲醛加氢制各高纯间苯 氧基苯甲醇。实验结果表明，PVP／Pt可以高选择性地催化醚醛加氢反应。 f21利用硼氢化钠作还原剂制备了铂和另一种金属的双金属合金纳米催化剂．。Ru和 Co的加入能提高催化剂的活性，当PtfRu摩尔比为5：1、Pt／Co摩尔比为7：1 时，双金属协同效应最明显；Cu、Au、Ni的加入不同程度的降低了催化剂的活 性．。 (3)利用不同金属离子对铂纳米金属簇进行离子修饰。结果表明，C02+、Fe2+、Ni2+离 子的加入能提高醚醛催化反应的活性，在优化的反应条件下，Fe2十修饰后的催化 活性是单金属铂催化剂的l倍多；Cu”、Zn”的加入使催化活性几乎丧失。 f41研究了PVP在铂金属簇上的热分解行为。通过热重差热分析发现，PVP在铂金属 簇上的分解与纯的PVP的热分解情况相差很大。TEM、IR、元素分析证实PVP 分解残留物仍然能对铂金属簇起保护作用，焙烧后颗粒粒径大约为5nm。 关键词：铂金属簇，间苯氧基苯甲醛，双金属簇，离子修饰，催化加氢 牟志刚 指导老师：杨平 高分子保护的铂系金属簇的制各、表征及对间苯氧基苯甲醛催化 高分子保护的铂系金属簇的制各、表征及对间苯氧基苯甲醛催化 英文摘要 Abstract (1)Poly(N-vinyl一2-pyrrolidone)(PVP)protected nanoclusters of platinum were prepared by all ethanol reduction method and characterized through TEM，UV-VIS．It used as catalysts in the hydrogenation of m—phenoxy benzaldehyde(MPBD)to form high purity ofm-phenoxy benzalcohol(MPBA)were studied．The results demonstrate that PVP-Pt displays high selectivity to MPBA． (2)Bimetallic nano—clusters were synthesized through the reduction of mixed salts by sodium borohydride．The addition of Co or Ru enhances the activity ofthe catalyst． The optimum catalysts carl be achieved with a Pt／Co mole rate of 7：1 and Pt／Ru mole rate of5：1．On the contrary,the addition ofCu、Au and Ni reduces the activity． (3)Polymer-protected platinum nano-clusters were modified by different metal ions．The activity hydrogenation of m—phenoxy benzaldehyde is promoted by the addition of C02+、Fe2+、Ni2+．Under the optimum conditions，modified by Fe2+，its activity is one times higher than the platinum nano．clusters alone．Cu2+and zn2+lead to lost the activity almost completely．Meanwhile the activity is effected by the concentration of PVP and pH value．When the ratio ofPVP and Pt is 40 and the pH value equals to 4．3， the highest activity is obtained (4)The thermal decomposition behavior of PVP on platinum is studied，which is quite different from the pure P