高分子聚合物在温度梯度下的结晶过程和形态发展-高分子化学与物理专业论文.docxVIP

高分子聚合物在温度梯度 环境下的结晶过程和形态发展 摘要 万方数据 Development of crystallization process and forms of polymer under Temperature Controlled Gradient Stage Abstract: The crystallization and growths of polymer were strongly affected by many factors, and the temperature plays an important role on the growth process of polymer and the final crystallization morphology. In this thesis, the nucleation, growth, morphology and the mechanism of biodegradable poly(3-hydroxybutyrate) was investigated by Polarizing optical microscope (POM), Atomic force microscope (AFM) isothermally, non-isothermally and under temperature gradient, respectively. The spherulitic growth process, kinetics behaviors and morphology of PHB thin films crystallized isothermally from the melt were observed by POM and AFM. And we conclude that the banded and non-banded spherulites were formed isothermally depending on different crystallization temperature. It was found that the competition of the crystallization rate of the crystalline entities of polymer entities and the diffusive displacement rate of melt molecules was employed to explain this. Both the crystallization rate and the diffusive displacement rate of melt molecules are very small in the lower crystallization temperature, the crystallization rate is bigger than the diffusive displacement rate of melt molecules with the increase of the crystallization temperature; however, the diffusive displacement rate is bigger than the crystallization rate as the crystallization temperature reached higher crystallization temperature. The corresponding morphology of PHB is non-banded, banded, non-banded, respectively. Meanwhile, the morphology of PHB is uniform circular due to the same growth rate in every direction. The spherulitic morphology of PHB thin films crystallized under temperature gradient from the melt was observed by POM and AFM not only determined by crystallization temperature but also determined by nucleation temperature and the position of nucleation. What’