改性凹凸棒土负载纳米铁的制备及性能表征建筑与土木工程专业论文.docxVIP

广东工业大学硕士学位论文酸根(C2042-)离子对改性凹凸棒土负载纳米铁去除Cr(VI)有不同程度的促进作用， 广东工业大学硕士学位论文 酸根(C2042-)离子对改性凹凸棒土负载纳米铁去除Cr(VI)有不同程度的促进作用， 且影响从大到小排序为H+C2042-S042。。C1。对改性凹凸棒土负载纳米铁去除Cr(VI) 有抑制作用。(4)改性凹凸棒土负载纳米铁对Cr(VI)的吸附符合准二级吸附动力学模 型。改性凹凸棒土负载纳米铁对Cr(VI)的吸附可用Langmuir吸附等温式描述，且改性 凹凸棒土负载纳米铁对Cr(VI)的吸附为有利吸附，吸附性能较好。 关键词：改性凹凸棒土；纳米铁；稳定性；Cr(VI)；性能表征 II 万方数据 ABSTRACTABSTRACT ABSTRACT ABSTRACT During twenty-first century,nano technology develop rapidly,which become a hot research in the field of science and get much attention by governments and technical workers．In recent years，as a new kind of nano materials，nanoscale zero valent iron has become a hot research topic in inorganic materials．The size of nanoscale zero valent iron is during 1-100nm，which has the characteristics of large specific surface area,strong reduction,etc．In the early days，nanoscale zero valent iron used for in-situ remediation of groundwater and at present it has been used in removal of chlorinated organic compounds， treatment of organic dyes or pesticides，removal of heavy metals and radioactive material． Although nanoscale zero valent iron has a lot of applications，it is prone to aggregation and easy oxidation in practical application．Therefore，solve the problem of prone to aggregation and improve stability has become a hot research for the use of nanoscale zero valent iron． The subject selected attapulgite which has the properties of rich，low cost，good settling，adsorption,modified and load performance．Acid treatment and microwave modification were used to modify attapulgite at first．And then with the modify attapulgite as supporter to prepare nanoscale zero-valent iron-support modified attapulgite．During the process of preparation,the attapulgite were characterized by orthogonal experiment to fmd the best preparation．The optimum conditions of modification were listed as follows：the iron and soil ratio 2．5：1，the concentration of acid 3mol／L，time of microwave 6min， microwave power 600W,the reaction time 24h．The nanoscale zero-valent ir