电学边界对纳米pbtio3点畴结构和热电效应的影响材料学专业论文.docxVIP

AbstractPhase Abstract Phase field metllod based on GiI曲u玛-Landau-D“onshire meory is applied to s砌y me eVolution of domain s仃uctI玳s aIld elec仃ocaloric e舵Ct (ECE) of 向Toelectric nalloparticles．The phase field删ions are numerically s01Ved by fiIlite dif|暗eIlce memod a11d fIour-order I№ge-l(吡a metllod．TWo-dimeIlsional siIIlulations of PbTi03(PTO)nanos仃uctures are perfomed under me intemediate(IM)elec仃ical bouIldary condition．The IM electrical bouIldary condition w淌paraIlleters Ao charact甜ze me de铲ee of compensation for me surface charges by me electrodes． 111erefore it caIl d撕匆 tlle influeIlce of d印ol撕zation elecmc 6eld aIld d印ol撕zation energy on tlle total eIle礓y When par锄eter Ao is zero，me sUd’ace cha略es are completely not compellsated wllich co玎esponds to open-circluit electrical boulldary condition．The sul?face ch鹕es are completely compensated as parameter Ao becomes iIlfiIlite，wllich Co仃eSponds to short-circuit ele嘶cal bouIldary condition． The numerical results showⅡlat me toroidal moment(G)of PT0 nanopaIticles wim Vortex domain蛐mcture decre弱es wim me increase of param酏er Ao．Finally t11e G decreaSes to zero tal(ing s嘶ce dla增p coII】【pensation into me n嗄 electrical boullda够111ere exists a砸tical par锄eter Value Acrfc=0．2S，which decides tlle sin酉e domain锄d Vortex domam smlctllres of fIen．oelectric nanomaterial at t11e room telllperatlJre．11ms me domain s仃uctu】旧of PTO naIlopamcles call be tImed by eI】叩loying meⅡⅥelectrical bouIldary condition．The loops of G as a劬ction of廿le applied curled electric filed are obtained llIlder me di妇融reIlt elecmcal bo吼dary conditions，wllich sMlll(s witll t11e increase of par锄eter Ao．And sh印e of me loops is tlle s锄e as P—E hysteresis loops．It caIl be fouIld mat me domain s仃ucn盯e switches f而m a single s臼mcture to a Vortex domain stnlcture unde唱oing a likely 900 domain stmcture witll me increase of me饥ded elec仃ic field as Ao=0-3．There exists a 1ikely Vortex smlcture near me sul?fIace．This Vortex domain stnlcture moVes to me center of me nan