SPS烧结Graphene2fSiBCN陶瓷与其高温性能.pdfVIP

Abstract Abstract SiBCN ceramic has outstanding stuctural stability, creep resistance and superior antioxidant that make it become one of the hotspots in the field of structural ceramics. However SPS sintering SiBCN bulk ceramic has low fracture toughness value along with poor performance of high thermal shock resistance and ablation resistance, researchs on the oxidation mechanism and the relationship between the microsturcture and the oxidation resistance were less . In this paper, we prapare Graphene by improving Hummers method in order to enhence the Graphene/SiBCN composite ceramic tougheness by SPS sintering. Through to the phase analysis and microstucture observation, the micro mechanism of Graphene/SiBCN ceramic will be well studied. In the interest of providing data support in engineering practice, deep reaearch will do in oxidation behavior, thermal shock resistance and ablation resistance of Graphene/SiBCN ceramic. The study found that natural flake graphite dealed with strong oxidation of concentrated sulfuric acid and Potassium Permanganate processing, lamellar spacing increases with prolonging the reaction time . The adding amount and adding time of Potassium Permanganate in this process plays a very important role. XRD, FT-IR and Raman spectrum analysis showed that, through oxidation process, the Graphene Oxide(GO), the Graphene(RGO) and the Graphite is significantly different in the structure. Through the SEM, TEM and AFM observation, the layer thickness of G