阴极极化对7050铝合金C-环应力腐蚀敏感性的影响-腐蚀科学与防护.PDFVIP

第27 卷 第3 期 腐蚀科学与防护技术腐蚀科学与防护技术 Vol.27 No.3 2015 年5 月 CORROSION SCIENCE AND PROTECTION TECHNOLOGY May 2015 阴极极化对7050 铝合金C-环应力腐蚀 敏感性的影响 金骥戎 宋仁国 祁 星 祁文娟 王 超 李 海 常州大学材料科学与工程学院 江苏省材料表面科学与技术重点实验室 常州 213164 摘要：采用阴极极化、扫描电子显微镜(SEM) 和定氢仪分析，研究了不同时效状态的7050 铝合金C-环在3.5% NaCl 水溶液中的应力腐蚀行为。结果表明：7050 铝合金恒位移试样C-环时效后的应力腐蚀敏感性(Iscc) 变化 规律为：Iscc 欠时效(135 ℃/8 h) ＞Iscc 峰时效(135 ℃/ 16 h) ＞Iscc 过时效(135 ℃/24 h) 。在一定范围内施加阴极极 化电位，7050 铝合金材料发生阴极腐蚀，从而促进裂纹萌生。对相同时效状态的7050 铝合金，C-环断口的氢 渗透速率随着极化电位的负移而增加，从而导致合金的Iscc 增加。 关键词：7050 铝合金 阴极极化 Ｃ-环试样 应力腐蚀 中图分类号：TG 178 文献标识码：A 文章编号：1002-6495(2015)03-0249-05 Effect of Cathodic Polarization on Susceptibility to SCC of C-ring Specimens in 7050 Aluminum Alloy JIN Jirong, SONG Renguo, QI Xing, QI Wenjuan, WANG Chao, LI Hai Jiangsu Key Laboratory of Materials Surface Science and Technology, School of Materials Science and Engineering, Changzhou University, Changzhou 213164, China Abstract: The effect of cathodic polarization on stress corrosion cracking (SCC) behavior of C- ring specimens of 7050 aluminum alloys of different aging states in 3.5% sodium chloride aqueous solution has been investigated, then the hydrogen content of the tested samples was measured by a hydrogen analyzer and the fractured alloy samples were examined by means of scanning electron microscope (SEM). The results showed that according to their aging states, the degree of suscepti- bility to SCC (Iscc) of 7050 aluminum alloy may be ranked as following: Iscc of under-aging (135 ℃/ 8 h) ＞Iscc of peak-aging (135 ℃/ 16 h) ＞Iscc of over-aging (135 ℃/24 h). When applying a cathodic polarizati