水-苯酚-碳酸二甲酯-正己烷液液相平衡的测定与关联-高校化学工程学报.PDFVIP

19 5 No.5 Vol.19 2005 10 Journal of Chemical Engineering of Chinese Universities Oct. 2005 1003-9015(2005)05-0686-05 , , ( , 100084) (DMC)20 DMC-- DMCUNIFAC DMC DMC DMC 50% 80% 10 19 UNIFAC OCOOOCOO CH H OACHACOH 2 2 UNIFAC O642.42 TQ 028.32 X703 A Experimental Determination and Correlation of Liquid-Liquid Equilibrium for Water-Phenol-Dimethyl Carbonate-Hexane System ZHANG Jing-tao, PIAO Xiang-lan, ZHU Shen-lin (State Key Laboratory of Chemical Engineering, Tsinghua University, Beijing 100084, China) Abstract: Dimethyl carbonate(DMC) was selected as green extractant to prevent the secondary pollution existing in current liquid-liquid extraction process using extractant with toxicity to recover phenol from water. Liquid-liquid equilibrium of ternary system water-phenol-DMC and quaternary system water- phenol-DMC-hexane was measured at 20 . The activity coefficient of DMC in the liquid phase was calculated by using model of UNIFAC. Experiments show that the distribution coefficient of phenol in organic and aqueous phases is a constant and doesn′t change with the phenol concentration in the aqueous phase, but the value of the constant is different for the extracting solvent with different initial volumetric concentration of DMC. The distribution coefficient of phenol is increased from 10 to 19 when the initial volumetric concentration of DMC in the extracting solvent is changed from 50% to 80%. A new UNIFAC group OCOO was defined in this paper and its interaction parameters with CH