介孔Al2O3分离富集-原子吸收法测定中药材中痕量铅镉铜的分析-分析化学专业论文.docxVIP

湘潭大学 湘潭大学 2009 级研究生毕业论文 II II Abstract The hyphenated technique of flame atomic spectrometry (FAAS) with solid-phase extraction(SPE) has been used in this paper，in order to determine the content of the trace heavy metal elements in traditional Chinese herbal medicine. The technology improves the selectivity and sensitivity of analysis method, but also reduces the matrix interference. The key in this paper is mesoporous separation material, it is a hot separation material with a high adsorption performance at present. This thesis in a reference on the basis of Chinese and foreign literature has synthetized a kind of high efficient adsorption materials which is mesoporous Al2O3, and with the flame atomic absorption as a method for detection.It has studied the process of separation and concentration of heavy metal ion in lead, copper and cadmium in Chinese herbal medicine with mesoporous Al2O3, and has set up a new method of high efficiency analysis of trace heavy metal element in traditional Chinese medicinal materials. The major contents were described as follows: The main determination method of heavy metals in Chinese traditional medicine were reviewed.The research and application during the adsorption materials and the technology of separation/enrichment in heavy metal analysis also were reviewed. The review emphasized on the mesoporous ma terials properties, synthesis and applications, and then came up with a new method of studying of trace Pb, Cd, Cu in Chinese herbal medicine determined by flame atomic absorption spectrometry after separation/preconcentration with mesoporous Al2O3. A mesoporous adsorption Al2O3 was self-made with sol-gel method and then it was characterized. The average pore diameter is 6.495 nm and the specific surface area is 224.595 m2/g. We has studied the mesoporous Al2O3 on lead adsorption properties under static conditions. The experiment discussed the solution acidity, temperature, time and the eluent on the separation and preconcentra