碱性动力电池铝合金阳极缓蚀剂的研究-材料物理与化学专业论文.docxVIP

中南大学硕士学位论文6．经一定的表面涂层处理后，铝合金阳极在80℃，添加GFH缓蚀 中南大学硕士学位论文 6．经一定的表面涂层处理后，铝合金阳极在80℃，添加GFH缓蚀 剂的5mol／LNaOH电解液中的析氢速率为O．184 mL／min．CI／12，电 解液体系缓蚀效率高达89．59％，且经表面处理后试样的电极电位 仍然较负，达一1．632V，说明表面涂层处理工艺是提高铝合金阳 极材料在高温强碱性电解液中综合性能的有效方法。 关键词：铝合金阳极、缓蚀剂、耐腐蚀性能、电化学性能 Ⅱ 中南大学硕士学位论文In 中南大学硕士学位论文 In this paper,the electrochemical behaviors of a novel aluminum alloy anode in alkaline solution with different inhibitors have been studied．田1e purpose of this essay is to find a suitable inhibitor which could optimize the anti—corrosion properties without affecting the electrochemical properties of the aluminum alloy anode．Modem examination techniques such as hydrogen production test, galvanodynamic(E-T curves)mcthods，potentiodynamic(Tafel curves) methods and SEM technique have been applied to analyze the electrochemical behaviors of aluminum alloy anode in alkaline solution (80℃，5mol／INaOH、．The results reveal that： 1．The novel aluminum alloy anode in alkaline solution(80(2， 5mol／LNaOH)has a high electrochemical activity and an negative electrode potential of—1．560V at a constant anodic current of 700mA／cm2．But the hydrogen production corrosion is very serious and the hydrogen evolution rate is high at 1．604m1．／min·cm2． 2．Among all the studied single inhibitors，KzMn04 has the best performance．When the concentration of K2Mn04 is 1．2mmol／L，the hydrogen evolution rate of aluminum anode is 0．442mL／min·cm2 and the electrode potential is-1．578V． 3．硼1c addition of Na2Sn03 can decrease the hydrogen production corrofion of the aluminum anode effectively and the hydrogen evolution rate of aluminum anode is low at O．352mIJmin．cnl2 in alkaline solution containing 5mm01／L Na2Sn03． 4．Acalcium citrate Can increase the electrochemical activation of the anode．When adding 1 5％(wt)acalcium citrate into the alkaline solution，the aluminum alloy anode has the most negative electrode potential of·1．698V． 5．Though single inhibitor has its own characteristic，it can’t satisfy the technical requirement of alkaline