碱性二次电池隔膜等离子体改性研究-材料学专业论文.docxVIP

碱性二次电池隔膜等离丁体改性研究 碱性二次电池隔膜等离丁体改性研究 中文提璺 碱性二次电池隔膜等离子体改性研究 中 文提要 本课题利用低温等离子体表面改性技术对碱性二次电池隔膜用丙纶非织造布进 行改性处理，分别研究了等离子体活化处理、等离子体引发溶液接枝聚合和等离子体 原位接枝聚合三种不同改性方法对丙纶隔膜的处理效果。 通过对处理前后丙纶隔膜进行的相关性能测试，系统地研究了各处理方法所涉及 的实验参数(反应气体、反应功率、反应时间、反应压强等)对隔膜改性效果的影响， 并利用红外光谱、光电子能谱、扫描电镜等仪器手段对隔膜表面的化学组成和形态结 构进行了表征分析。 研究结果表明，通过以上三种表面改性处理方法，都可以在丙纶隔膜表面引入亲 水性基团，改善隔膜的浸润性，使其吸碱速率和吸碱量显著提高，面电阻大幅降低， 同时对隔膜的力学强度影响不大，隔膜的整体性能达到了国外同类产品水平。 关键词：电池隔膜丙纶非织造布等离子体表面改性 作 者：刘波 指导教师：王红卫 Study Study Plasma Modification ofAlkali Rcch——argeable Ba．．．t．．t．e．．．r．．y．．．．．S．．．e．．．p．．．a．．．r．．a．．—to—r AbstPact Study on Plasma Modification of Alkali Rechargeable Battery Separator Abstract The surface ofpolypropylene nonwoven fabric WaS modified by cold plasma treatment for alkaline battery separator in this paper．The surface treatment Was carried out in three different methods as plasma activation treatment，plasma initiated trait polymerization and plasma polymerization respectively，and the treatment effect of PP battery separator was studied． Through the related performance tests of original PP separator and plasma modified PP separator,the involved treatment parameters of all methods above were studied systematically including gas atmosphere,plasma power,treating time,treating pressure etc． Moreover，IR，XPS and SEM were used to characterize the surface properties of the samples such as chemical composition and morphological structure． The results show that certain hydrophilic groups were introduced onto the surface of PP separator by above three different methods of surface modification treatment，and the separator hydrophilicity Was improved．The alkali absorption velocity and quantity of separator increased obviously,whereas the electrical resistance decreased greatly without much loss in mechanical strength．As result，the performance of PP battery separator Was improved greatly and reaches the level of foreign kin product． Keywords：battery separator；polypropylene nonwoven fabric；plasma；surface modi6cation Written by LiuBo Supervis