碱金属K和Na对配合煤炼焦特性及捣固焦炭质量影响的研究-化学工程与技术专业论文.docxVIP

到43．2％，CSR从56．5％减小到48．5％。通过添加0．5％的TiB2可以抵消配入30％ 到43．2％，CSR从56．5％减小到48．5％。通过添加0．5％的TiB2可以抵消配入30％ 的青海木里高碱煤对焦炭热态性能的影响。 关键词：碱金属；炼焦特性：焦炭质量：高碱煤；硼化钛 万方数据 Ab Ab stract Qinghai Muli coal is a kind of high-alkali coal with a certain caking capacity and a high amount of K and Na．In order to make good use of the high-alkali coal for tamping coking，it is absolutely necessary to study the impact of K and Na on coking characteristics of blending coal and properties of tamping coke．The purpose of this dissertation was to research the impact of K and Na on coking characteristics of blending coal and properties of tamping coke and relatedly mechanism，explore effective ways to reduce the influence of Na and K in coal and finally provide some ideas for the use of high-alkali coal in coking． First，a certain amount of alkali metal carbonates were added into the blending coal of 5．5 m tamping coke oven in LianGang．Then the influences of K or Na on the volatile matter，the caking and coking properties and the pyrolysis of blending coal were studied．5 kg tamping-coking experiments were carried out．Then the influences of K or Na in blending coal on the cold strength，the thermal properties，the microcrystal structure and coke optical texture of coke by 5 kg tamping-coking experiments were studied．And the mechanism of coke properties effected by K or Na was investigated from the coking process．Then the research of reducing the influence of K or Na in blending coal on coking characteristics of blending coal and properties of tamping coke was done by adding H3803 or TiB2．The effect of the two methods was compared．Finally，5 kg tamping-coking experiments by using blending coal with the addition of Qinghai Muli high-alkali coal and TiB2 were carried out based on the previous studies．And we got the following conclusions： (1)K or Na catalyzed the pyrolysis of blending coal and reduced the pyrolysis activation energy at 400。C-600。C．The volatile matter of blending coal increased，the G and Y of blending