甲烷在燃料型溶剂中溶解度的研究-化工工艺专业论文.docxVIP

摘要由于环保意识的加强斧Ⅱ汽车工业的发展，汽车慰气污染日益为人 摘要 由于环保意识的加强斧Ⅱ汽车工业的发展，汽车慰气污染日益为人 类掰重强，稳鼹淳涪、经浇滟天然气汽攀褒戒燕魂今鹾究静重点，瓣 前天然气汽车存在着储罐臌力过高及不发全等问题，因此天然气汽车 急需解决的闽题就是如何爨现天然气经济、高效地贮存，其中将天然 气滚诧是貉决天蒸气汽车广泛镬雳靛蠢效途径之一。 在查阅大量文献的基础上，详细分析了甲烷在烃必溶剂中的溶解 度的规律，分析了温度、联力及溶剂结构对甲烷溶解度的影响，并酋 次疆窭了亭翻系鼗襄溶裁赣爨薅积魏关联式，这委了瀵意豹结果。 自建了一套测定高压下气体在溶剂中溶解度的实验装置，并选择 文献数据对实验装鹭进行了检验，证实了其可靠性。酋次提供了齑压 F擎浣在不蠲的瀣凄、浓度’F予乙藜与囊基靛、歪获烷、舔己烷等混 合溶剂中的溶解度。通过对实验数据进行分析，表明猩该实验的温度 和压力范围内，甲烷在这贱溶剂中基本符合亨利定律。 鬟震襞褥黪实验数摇滚行了关袋，撬窭了亨弱系数蠢滠褒、滚裁 浓度以及同时含有温度和溶剂浓度的三个关联式，关联误差较小，浅 明用此关联式预测和推算甲烷在这些溶荆中溶解度，实验结果是可箨 鹣，瓢蠢为逸簿天然气汽攀燃耨豹磷究撬筷’≯诗算方法。 关键词t天然气汽车燃料、甲烷、溶解嶷、气渡·平衡、亨利系数 ABSTRACTWith ABSTRACT With the improvement of environment consciousness and development of vehicles，the ej ected gases from vehicles are more emphasized．Relatively clean and economically natural gas vehicles become the emphasis of research．But there are some problems such as the fuel tank’S higher pressure、other unsafeties and SO on。So the very urgent problem for natural gas vehicle is to how to store natural gas economically and efficiently．Liquefying natural gas is one effective way for putting natural gas vehicle in wide use。 On the basis of many literatures，the law of methane solubility in alkanes was particularly studied by analyzing temperature、pressure and solvent structure’S effect on methane solubility，The correlated equation of Henry’S coefficient and critical volume were first advanced．The results are sati sfactory． One experiment equipment for measuring the solubility of gas in solvents under higher pressures was set up．It was validated with literature data and proved well the availability．Methane solubilities in mixed solvents of ethanol+hexane，heptane，cyclohexane and SO On were gotten，Solubility data of methane in these solvents under experimental temperatures and pressures were corresponded with Henry law． The three correlated equations of Henry’S coefficient with temperature、solvent concentration and temperature combined with solvent concentration were advanced by using experimental data，the e