秸秆预处理及用改性脲醛胶制造纤维板的研究-林产化学加工工程专业论文.docx

RESE越己CH RESE越己CH 0N MAⅫJF：ACH『I{蹦G OF MDF FRoM RICE AND WHEAT STRAWS WITH MODIF正D UF RESN AND PREⅡ也ArED STRAW Due to the particularities of raw materials and the surface substances which inhibit water-based resin bonding，medium density fiber boards OVIDFs)from rice straw and wheat straw bonded with conventional urea-formaldehyde resin(uD do not have satisfactory properties as required,and commercial production line of those kinds of MDFs has not been built yet in China．，In order to provide some theoretical foundation for manufacturing MDFs from rice and wheat straw，this research work dealt with the manufacturing optimization,performance modification and structure of the environment．friendly UF resin,investigated the influences of straw pretreatment both with chemicals and biology enzymes on the properties ofthe straw fiber boards bonded witll UF resin,analyzed the differences existed among different layers of straw stalk and discussed the mechanism ofmanufacturing straw MDFs by different pretreating us well． The following conclusions were drawn based on the research： 1．Urea-formaldehyde resin modified with Melamine(MUF)was a proper resin to bond rice and wheat straw fiber boards．and Was an altemative to MDI resin in this application．The best 1 synthesis parameters ofthis resin were as follows：MOOre ratio offormaldehyde to urea was．3，the pH value ofthe synthesis was 4．9-5．0，the reaction tcmpemture Was 85[3，and the addition amount ofthe melamine was 5％． 2．By analyzing ofmechanism ofUF and MUF resins which prepared at the same molar ratio，it was found that the degree of glue joining improved with lower contents of methylol end groups and lligher resistance to water attack．And DSC showed that MUF resin demanded higher curing temperature compared to UF resin．The surface tension of the MUF resin Was 6．3％less than that of UF resin．hence the wetting ability of MUF to sllaw fibor Was improved．which was good for MUF glue to diffuse and penetrate into fiber element and resul