焦化废水中氰化物和色度处理的试验研究-环境工程专业论文.docxVIP

太原理工大学硕士研究生学位论文左右。单独使用混凝沉淀法，难以使焦化废水达到国家排放标准。 太原理工大学硕士研究生学位论文 左右。单独使用混凝沉淀法，难以使焦化废水达到国家排放标准。 2．单独使用氧化法时，在4～40mg／L加药量范围内，二氧 化氯的处理效果较好，氰化物的去除率可以达到85％以上，色度 达到60％以上。单独使用氧化法，采用氧化N--氧化氯处理焦化 废水，氰化物能够达到国家二级排放标准，而色度难以达标排放。 3．在混凝剂中聚铁受pH值的影响相对较小，并能达到较好 的处理效果。二氧化氯的氧化能力受pH值的影响很大。在pH值 为8～10时，氰化物和色度的去除率比较理想。 4．温度对氰化物和色度去除率的影响很大。当水温小于20。C 时，混凝沉淀和氧化法对氰化物和色度的去除率的效果都很差； 水温在25 6C以上时，氰化物和色度去除效果比较明显。考虑生化 处理后出水水温为30℃左右，混凝沉淀一氧化法的实验水温取 30℃。 5．运用正交实验的方法，找出了焦化废水中氰化物和色度处 理的药剂最佳投药量为：p(聚铁)．30mg／L，pH=9，p(c102)．2Drag／L， p(PAM。3．5mg／L；其处理效果为：色度去除率为88．6796,氰化物的 去除率为91．3％，CODCr去除率达到了68．1％ 关键词：焦化废水，混凝沉淀一氧化法，正交实验，最佳方案， pH值 2 奎堕墨：!：盔兰堡主婴垄竺兰堡笙奎 奎堕墨：!：盔兰堡主婴垄竺兰堡笙奎 ． TRY AND RESERCH 0N CHROMA AND CYA NⅡ)E TREATⅣ匝NT OF COKE PLANT WASTEWATER ABSTRACT Components were complex in coke plant wastewater,in which contains refractory organic compounds such as tar、benzene、 phenol、cyanide、quinoline and pyridine etc．So chroma of that is hi曲，and great changes happened usually to water quality and water flow．It is a typical industrial wastewater,in which contains a number of toxic and nocuousness compounds．The biological treatment processes deal with coke plant wastewater,which chroma and cyanide of removal rate are not favorable and the effluent concentration couldn’t attain the wastewater drainage level，which brought severe harm to our environment and human body．It had been demonstrated that adopting flocculating and depositing—oxidation depositing—oxidation deal with cyanide and reduce chroma in coking．plant wastewater after bioglogical treatment process is a cost effective technology In this research，with the use of A13S04、PAC、PFS、PAM、 ，， NaCIO、C102 ect．alone or combination，dealing with cyanide and reducing chroma in coking·plant wastewater was analysed an．d researched．Besides with the way of experiment，the best of throwing agents project and quantity of agents was suggested．The results are as follows： 1．Using alone the way of flocculating and depositing，it was the best relatively method that adopt