胶原蛋白改型聚丙烯腈的初步研究-皮革化学与工程专业论文.docxVIP

郑州大学硕士学位论文Abstract 郑州大学硕士学位论文 Abstract The leather industry is a traditional industry which is characterized by high investment and low output．Only about 25％of the materials in raw skins or hides can be transformed into leathers in the processing of leather making．As a resuR，both serious pollution to the environment and waste ofvaluable resources are caused ifthe tannery waste is abandoned or decomposed．According to the principle of‘Green Chemistry’，the resource and value of collagen is studied in the paper with the aim of using the collagen from tannery waste in textile industry． The polyacrylonitrile(PAN)fiber has advantages such as flexibility，good mechanical performance，ere．However,the poor dying ability and mechanical performance limit its application in textile industry．At present，the use of protein to modify the polyacryionitrile fiber has been reported,but no study may be found to use collagen from tannery waste to modify the polyacrylonitrile fiber． In the present study，collagen Was used to modify the polyacrylonitrile fiber by solution polymerization of collagen and acrylonitrile．Effects of monomer concentration，initiator concentration,reaction temperature and reaction time on the copolymerization conversion,polymer concentration and intrinsic viscosity Was investigated．The spinaability of solution Was also studied,and the theory of the polymerization Was discussed．It has been shown that the best polymerization conditions of collagen／AN arethe reaction temperature is 60C，the concentration of initiator iS l％，the concentration ofmonomer iS 20％，the mass proportion ofcollagen to AN is 2 to 98，and the reaction time is 8h．A theory for the spin application of solution polymerization ofcollagen／acrylonitrile is provided． Keywords：collagen，acrylonitrile，copolymerization，conversion，spinnability 郑州大学硕士学位论文引言 郑州大学硕士学位论文 引言 制革这个古老的行业极大地丰富了人们的物质生活，同时也带来了严重的环 境污染和资源浪费。中国皮革工业每年约有140万吨的固体废弃物，这些废弃物 中含有大量性能优良的蛋白质，是宝贵的生物资源。近年来，虽然众多的科研工 作者在皮革废弃物处理上做了大量的工作，在胶原蛋白的回收再利用业方面也取