焦化液收添加剂及炉管缓焦剂的评价与开发-化学工程专业论文.docxVIP

石油大学(华东)硕士论文 石油大学(华东)硕士论文 摘要 ABSTRACT EVALUATING AND DEVELOPMENT OF ADDITIVE TO IⅣIPROVE LIQUID YIELD OF COKING A ND ADDITIVE TO DECREASE COKE IN唧COKING FURNACE Evaluating additive of coking accurately was difficult the spot．The difficulty to evaluate additive如the laboratory was control reaction process of different experiment just the salne．In this paper,the technique of evaluating additive and concoction of coking subminiature apparatus for heavy oil thermal conversion was researched the basis of parallel model for thermal conversion of heavy oil．In order eliminate the influence of reaction process，the concepts of percent conversion function，experimental relative light oil yield efficient，experimental relative coking efficient．theoretic light oil yield．theoretic matrix yield of coke，etc，were put forward．In order eliminate artificial and analytic error，the concepts of uncertain interval of experimental evaluation，etc， were put forward．Then some additive to improve liquid yield of coking and some additive to decrease coke in the coking furnace were evaluated． The technique of evaluating the influence of concoction’S mixing proportion light oil yield of coking was expanded the basis of the concept“light oil yield vacuum residue”．Then the influence ofparaffin oil of coking and catalytic—oil suspension in the cokirig stock light oil yield of coking was evaluated by experiment． KEY WORDS：coking；additive；method of evaluating；additive improve liquid yield；additive decrease coke；concoction of coking 石油大学(华东)硕士论文 石油大学(华东)硕士论文 前言 月IJ罱 与重油加氢及催化裂化工艺不同，重油热加]亡艺是在没有催化 剂存在的情况下，利用重油在高温下发生化学反应而达到轻质化目的 的工艺方法。尽管得到的产品须通过后续过程处训，由于其具有对原 料适应性强、能耗和加工费用低及设各投资费用低¨】等特点，广泛应 用于处理各种重质馏分油、残渣油及硫、氮、氧、蕈会属、沥青质杂 质含量高的原料油。事实上，重油热化反应一直是重油轻质化的主要 途径。 焦化反应是重油热化反应中的一种，我国是延迟焦化大国，目l；i『 有延迟焦化装置20余套，加工能力仅次于美国，居世界第二位。由 于我国前段时期对延迟焦化工艺重视不够，操作水平与国外先进水平 存在很大差距，以焦炭产率为例，国外先进技术焦炭／残炭产率之比已 降到1．27，国内焦炭／残炭产率之比平均水平为1．82【2】。目前，鉴于重