金属和半导体纳米结构构筑及表征-无机化学专业论文.docxVIP

金属和半导体纳米结构构筑及表征 金属和半导体纳米结构构筑及表征 摘要 中文摘要 在光滑银表面上以l，4一二巯基苯为藕联分子组装了CdS纳米粒子。SEM和共振拉 曼光谱研究表明，CdS在组装后仍然保持纳米粒子特征，且在银表面形成二维亚单层 结构。FT一拉曼光谱表明1，4一二巯基苯以相对基底表面倾斜的取向藕联于CdS纳米粒 子和银表面之间，并且组装的CdS纳米粒子对藕联1，4一二巯基苯的拉曼散射具有明显 的增强效应。以3一巯醇基丙基三甲氧基硅烷(3-mercaptoprophltrimethoxy sillane) 为藕联分子，在玻璃上组装了金、银纳米粒子，研究了它们的紫外吸收光谱。 利用微乳液法制备了平均粒径约为600nm的聚苯乙烯纳米粒子，在溶剂挥发过程 中，聚苯乙烯纳米粒子采用典型的立方面心(FCC)密堆积结构排列形式自发地在基底 表面形成单层或多层自组装规则结构。以此为模板，用尺寸相对较小的金纳米粒子(～ 15nm)填充进入聚苯乙烯的密堆积空隙中，除去聚苯乙烯模板后，在原聚苯乙烯纳米 粒子底部得到金纳米粒子自组装聚集成的规则“面包圈”结构，完成了金纳米粒子的 图案化组装。而且，还可在聚苯乙烯模板上化学镀银，得到有序排列的银纳米结构。 比较了金纳米粒子组装体的对巯基苯甲酸表面增强拉曼光谱，以及纳米银结构上对巯 基苯的表面增强拉曼光谱。 关键词：表面增强拉曼光谱，聚苯乙烯，纳米粒子，CdS，自组装 作者：赵宏 指导教师：周群 Narl0．sizedArchReeatms Narl0．sizedArchReeatms ofMemls and Semiconductors and Their Charaterizations Abstract Abstract CdS nanoparticles were assembled on smooth silver surface by using 1,4一benzenedithiol a,s coupling molecule．SEM and resonance Raman spectroscopic characterizations demonstrate that the n盟ostructure of CdS was preserved upon assembly, and a two—dimensional structure of CdS nanoparticles was formed on the substrate surface． FT-Raman spectra indicate that 1,4一benzenedithiol was coupled between CdS nanoparticles and silver surface with a tilted orieatafion．The RaRlan scattering of 1,4-benzenedithiol was substantially enhanced by the assembled CdS nanoparticles．Gold and silver nanoparticles were assembled on glass by absorbed inorganic molder Polystylene nanoparticles of diameter 500nm was made by emulsion polymerization． After evaporation ofsolvent water,an ofdeI℃d structure ofpolystylene nanoparticles call be spontaneously generated on a solid substrate，forming particle monolayer or multiplayer, which provide the template for metal deposition．Gold nanoparticles(，15am)Call be filled into the opened space formed among polystylene nanoparticles．As a resuk，gold nanoparticles、)lf雠assembled in a patterned manner by using an assembly of polystylene nanoparticles as a template．A‘do