原电池热力学可逆电动势与电池反应的吉布斯函数变研究意义.pdf

7.6 1 2 G = W G = W =QE r r r d∆ G δW −zFdξE r r ⎛∂∆ G ⎞ ∆ G ⎜ r ⎟ −zFE r m ⎝ ∂ξ ⎠ T , p 1 G r m 2 7.6 2S r m ⎛∂∆ G ⎞ r m =−∆ S ⎜ ⎟ r m G = zFE ⎝ ∂T ⎠p r m ∂E ⎛ ⎞ ∂E ∆S z F ⎛ ⎞ r m ⎜ ⎟ ⎜ ⎟ ∂T ⎝ ⎠p ∂T ⎝ ⎠p ∂E ⎛ ⎞ 3E ⎜ ⎟ H ∂T r m ⎝ ⎠p - ∆ G ∆ H −T∆ S r m r m r m ∂E ⎛ ⎞ ∆r H m ∆r Gm +T∆r Sm −zFE +zFT ⎜ ⎟ ∂T ⎝ ⎠p ∂E ⎛ ⎞