离子色谱串联质谱用于净水树脂中14种胺类固化剂迁移量方法建立和应用.docxVIP

离子色谱-串联质谱用于净水树脂中14种胺 类固化剂迁移量方法建立和应用 ［摘要］欧盟最新指令新法规(EU) No. 10/2011对 胺类物质的迁移限量进行了规定。本文研究饮用水净化树脂 中14种胺类固化剂的迁移量检测方法，选用高容量阳离子 交换柱IonPac CS17 (2mm)进行分离，以甲烷磺酸(MSA) 为淋洗液，采用梯度淋洗。淋洗液经过抑制器后直接进入质 谱(ESI-MS),正离子模式进行检测。建立了 一种同时测定 树脂中14种胺类固化剂迁移量的离子色谱-串联质谱方法。 该方法的加标回收率为76.5%?104.8% ,相对标准偏差 (RSD)为0.94%?10. 7%,该方法简便快速，可用于树脂中 胺类固化剂迁移量的同时测定。 ［关键词］胺类固化剂；饮用水净化树脂；离子色谱/串 联质谱法 中图分类号:0657文献标识码：A文章编号:2055-5200 (2014) 01-064-05 Doi： 10. 11876/mimt201401017 Detection? of? the? migration? of? 14? amines? curing ? age nt? in? water ? purif ica tion ? resins ? by ? ion-chromatography/electrospray tandem mass spectrometry LIU Xu~hui, TANG Shu—tian, GAO Feng, LIU Xin, CHENG Xi-ming, ZHANG Zhao-hui, LIU Yan. (Technical Center, Beijing Entry~Exit Inspection and Quarantine Bureau, Beijing, 100026) [Abstract] In the new EU Directive (No. 10/2011), amines curing agent in water purification resins was given their limitations? In this paper, a method was established to simuItaneously determine the migration of 14 amide curing age nt used in the resin for wa/ter purification by using ionchromatography/electrospray tandem mass spectrometry (IC/ESI/MS)? Amide curing agents were separated with high capacity and cation exchange column using MAS eluent gradient online from EGC? The recoveries are in the range of 76. 5%?104.8% while the relative standard deviation (RSD) ranges from 0. 94% tolO. 7%. This method is simple and rapid, which is applicable for the simultaneous determination of amide curing agent migration of 14 amides curing agent used in the resin for water purification. [Key words] amines curing agent； water purification resins ； ion-chromatography/electrospray tandem mass spectrometry 由于普遍认识到反复烧开的水会引起致癌物质亚硝酸 盐含量的升高，所以越来越多的人选用直饮式饮水机。然而 采用离子树脂净化的饮水方式并不如人们想象中的那样安 全。饮水机用离子交换树脂的原料大都采用胺类固化剂以改 善其使用性能。常用的胺类固化剂有脂肪族多元胺及其改性 物、聚酰胺树脂固化剂及其改性物、酚醛胺类固化剂、芳香 族胺类固化剂等。通过对胺类固化剂的毒性研究显示胺类固 化剂毒性是比较强的，有些胺类物质还会引起肝脏和肾脏的 损伤[1-4] o具有较大的全身毒性，多数胺类物质甚至还具 有致癌性。二甲胺、二乙胺是致癌物亚硝胺的前体物。对称 的亚硝胺可引起肝癌，不对称亚硝胺会引起食管癌。如果这 些生产中残留的胺类物质在过滤过程中迁移到日常大量