基于三蝶烯结构含氟二胺改性的双马来酰亚胺树脂和新型聚酰亚胺材料的合成与性能研究-有机化学专业论文.docxVIP

Ab Abstract PAGE PAGE III ABSTRACT Polyimides and bismaleimides have been widely used in the field of high technology such as solar photovoltaic, aerospace, military technology because of their beneficial characteristics of thermal stability, hygrothermal resistance, irradiation resistance, and chemical resistance. Bismaleimides derivate from polyimides and are machined easily like epoxy resin contrast to polyimides but their low thermal stability. therefore, they are often served as the matrix of composites. Unmodified Bismaleimides suffer from the drawbacks of poor solubility, high processing temperature and brittleness after curing which make investigations on modification of BMI be active in research area of polymer. Aromatic polyimides showed poor solubility, low transmittance, high dielectric constant and poor processing due to the effect of rigid molecular structure, crystallization and electron polarization. To address above problems, researchers conducted a lot of research on the modification. Aimed at above problems, main content includes the modified bismaleimide and synthesis of novel polyimide material in this paper. In the aspect of modification of BMI, commercial BMI was improved from the reaction of miachael by diamine containing triptycene and fluorine, compared with bismaleimide modified by ordinary diamine in performance. On the other hand, the novel diamine was based on former diamine which was superinduced fatty chain with triptycene and fluorine.The new PI films were synthesized by the novel diamine with commercial aromatic dianhydrides, and the ordinary diamine without triptycene participated in the comparative experiment. Our work was mainly divided into four parts. Firstly, the maximum yield of 1,4-Dihydroxytriptycene was synthesized in two steps from the reaction D-A of industrialized and cheap anthracene with p-benzoquinone followed by proton rearrangement under acidic conditions.We obtained two types of binitro by nucleophile substitut