含稀土盐复合电解液体系中ZAlSi12合金表面微弧氧化膜的形成及表征-材料加工工程专业论文.docxVIP

Abstract Cast aluminum alloys are wide applied in industry field due to its low density ,high specific strength and excellent processing properties.However, the poor wear resistance which has restricted the application of unprotected aluminum alloys, Micro-arc Oxidation is an effective and promising surface treat technique ,by using MAO method ,the film which situ-growed on the substrate can obtained . Consequently ,the hardness, wear resistance and corrosion resistance of the alloy was improved. The mechanism that the electrolyte have on the MAO process and characterization of ceramic coating were very complexes until now ,it hasn’t made an unique and definite cognition ,so there have many work to do to study the composition of electrolyte . The ceramic coating were prepared on the surface of ZAlSi12 alloys and a high power supply unit (WHD-30) treatment device was adopted for MAO process ,the potentiostatic method was adopted in this work ,the applied positive/negative potential of the acyclic was 420/120V respectively, predefined frequency at 100HZ,current density variated with the automatic adjustment ,an aqueous alkaline electrolyte of Na2SiO3 8.0 g/L + NaOH 2.0 g/L + EDTA 2.0 g/L was formulated, an appropriate amount of additive Ce(NO3)3、La(NO3)3、 Ce(SO4)2·4H2O 及 Na5P3O10 were added into Na2SiO3 -NaOH (alkali-silicate)electrolytic system. The regularity that the effect of additive concentration and have on the characterizations of coating were investigated ,the coatings were characterized by eddy current thickness meter,SEM,XRDand EDS analysis methods .the result show that :the thickness of ceramic coating increased after added Ce(NO3)3 into electrolyte and the max value reach to 170μm,the coatings formed in the electrolyte contained Ce(NO3)3 are still composed by α-Al2O3 phase and γ-Al2O3 phase ,but the proportion of α-Al2O3 phase increased after added Ce(NO3)3 into electrolyte ;the thickness of the coating increased with the content of La(NO3)