硅系延期药配方及延期元件工艺研究-应用化学专业论文.docxVIP

万方数据 万方数据 摘 摘 要 捅 要 本文较全面的介绍了延期药的国内外研究现状和基本理论以及影响因素，并 以硅系延期药为研究对象，采用自制模具，运用光电测试法，测试不同直径延期 元件对延时的影响。并选用铬酸钡作为第二氧化剂加入硅系延期药中，制备出符 合高段别毫秒延的延期药。同时，利用X射线衍射对添加铬酸钡的硅系延期药的 燃烧产物进行分析，了解该类型延期药可能存在的化学反应。为进一步减缓硅系 延期药燃烧速度，以添加铬酸钡的硅系药剂为基础，添加三种不同缓燃剂，探讨 缓燃剂对高段毫秒延期药延期时间的影响。经过试验测试，得出以下结论： (1)随着拉拔次数的增加，药柱直径逐渐减小，延期元件直径为3．0mm时，其 燃烧速度最快，并且燃烧最为稳定。 (2)对于添加铬酸钡作为第二氧化剂的硅系延期药，随着铬酸钡含量的升高， 平均燃速逐渐减慢。并且铬酸钡自身在分解后，其产物出现自身继续被氧化现象。 (3)对基础药剂添加冰晶石和硒粉缓燃剂后，最长延时可以达到2s，同时延期 精度有所提高。但添加复合缓燃剂后，可燃剂含量过低时，不能保证发火稳定性。 (4)添加氟化钙作为缓燃剂，随着氟化钙含量的升高延期时间有较大程度的增 加，燃速最低可以降至0．61cm·S～，并且其添加含量5‰8％之间时效果较好。同 时可燃物含量的升高可以较好的保证其贮存稳定性。 图39表22参54 关键词：延期元件直径；铬酸钡；缓燃剂；延期时间；延时精度 分类号： 安徽理工大学硕士学位论文 -11- AbstractAbs仃act Abstract Abs仃act Research status，basic theories and influencing factors about delay composition were mainly in仃oduced in this paper．Using moulds by self-designed，the photoelectric test methond Was used to test the effects of delay elements with different diameters on delay of sillicon delay composition．And Barium chromate Was selected as auxiliary oxidant to prepare high period millisecond delay composition．At the same time，to understand the possible chemical reactions of this delay composition，combustion products of silicon delay composition doped with barium chromate were analyzed by X—ray diffraction．In orde to further slow down the burning rate of silicon delay composition，based on silicon reagent loaded with barium chromate，three kinds of slow burner were added to investigate the their effects on delay time of millisecond delay composition．And the conclusions were drawn as follows： (1)With the number of the drawing times increasing，the column diameter decreases grad砌ly,when the diameter of the delay element is 3．00 ITlnl，the buming rate is the fastest．Meanwhile，the combustion is the most stable． (2)For barium chromate as the auxiliary oxidant,with increasing the content of barium chromate，the average buming rate gradually slowed down．And after decomposition of barium chromate，the products appear to continue to be oxidize