砌体结构设计中的几点意见.DOC

PAGE 4 二氧化氯治理过渡层技术实验研究 朱兆阁 摘 要:过渡层是油水分离过程中产生的一种有害物质，对原油脱水系统和污水处理系统具有很大影响，能够导致电脱水器电流升高、跨电场等严重后果。为了保障原油脱水系统平稳运行，开展了过渡层治理技术研究，从测定的过渡层组分得出其构成中含有大量的聚合物、胶质、沥青质及硫化亚铁（FeS），通过对过渡层物性和成因分析，确定沥青质及胶质的乳化作用、FeS等固体颗粒的促进作用、聚合物的强化作用是形成过渡层的重要原因，其中FeS等固体颗粒是形成稳定过渡层的主要原因。利用FeS的不稳定性，确定了氧化处理方法，采用氧化剂二氧化氯对过渡层进行处理，通过单因素实验和正交实验确定了浓度、温度及反应时间等运行参数，并在现场生产应用中进行了参数调试，确定二氧化氯加药浓度190mg/l、反应温度50-55℃、反应时间5h条件下，能够对过渡层进行有效处理，脱水率达到99.27%。为过渡层治理提供了技术依据。 关键词：过渡层；二氧化氯；硫化亚铁；脱水率 Experimental study on treatment of transition layer with chlorine dioxide Zhu zhaoge Abstract：Transition layer is the oil-water separation process of a kind of harmful substances，for crude oil dehydration system and sewage treatment system has a great influence，can result in higher electric dehydrator current serious consequences，such as electric field. To secure crude dehydration system running smoothly，to carry out the transition layer management technology research，from the transition layer composition the composition contains a large number of polymer，colloid and asphaltene and ferrous sulfide (FeS)，through the transition layer property and cause analysis，to determine the role of asphaltene and glial emulsion，FeS，polymer solids such as promoting effect of reinforcement is the important reason for the formation of transitional layer，including FeS and other solid particles are the main reasons for the formation of stable transition layer. Using instability of FeS，oxidation treatment method was confirmed， the oxidant chlorine dioxide to deal with transition layer，through the single factor experiment and orthogonal experiment to determine the concentration，temperature and reaction time on operation parameters，and the parameters in the scene production application debugging，to determine the concentration of chlorine dioxide dosing 190 mg/l ，50 to 55℃ reaction temperature，reaction time of 5 h condition，can effectively deal with the transitional layer，the dehydration rate of 99.27%. Provides technical basis for transition layer and cont