规模化猪场废水氨氮对厌氧微生物活性的影响及生物脱氮的研究-环境工程专业论文.docxVIP

规模化猪场废水氨氮对厌氧微生物活性的影响及生物脱氮的研究 规模化猪场废水氨氮对厌氧微生物活性的影响及生物脱氮的研究 摘要 氨氮对厌氧微生物的活性有一定的影响，规模化猪场废水在厌氧消化 过程中，由于氮化作用，强化了这一影响作用。通过厌氧毒性测定试验及 污泥活性恢复试验，研究模拟废水及猪场原水氨氮对厌氧微生物活性的影 响。结果表明，模拟废水氨氮对厌氧颗粒污泥产甲烷活性的影响具有多重 性，当氨氮浓度低于400mg／L时，表现为促进产甲烷作用。当氨氮浓度为 800mg／L时，开始表现为抑制产甲烷作用，并且随着氨氮浓度的升高，抑 制作用增强。猪场原水在进水浓度下均表现为抑制作用。模拟废水50％抑 制浓度为1900．1mg／L，猪场原水50％抑制浓度为1725．9mg／L；在相同的抑 制程度下，模拟废水氨氮浓度均高于猪场原水，平均相差594．1mg／L。 原水氨氮浓度及消化体系pH环境对消化过程中氨氮转化率及有机物 的去除率均有影响。试验表明，原水氨氮浓度越高，氨化率越低，但COD 去除率越高。在pH=7．0，7．5，8．0的试验范围内，pH=7．5的消化体系氨化 率最高；pH三7．0的体系COD去除率及产气量均最高，pH-7．5稍低，两种 体系均远高于pH=8．0体系。氨氮转化速度很快，在前4h即能完成大部分 氨化，结合COD去除效果，厌氧消化时间宜为24h，pH宜为7．5。 通过厌氧颗粒污泥好氧化培养，经过53d培养驯化后，氨氮浓度达 716．8mg／L，去除率为98．2％，COD去除率为90％，进入正式试验阶段。试 验确定SBR处理猪场废水厌氧消化液脱氮工艺的最优工况为：瞬时进水后 缺氧搅拌40min+6h前段曝气+60min后段缺氧搅拌+40min后段曝气+ 1h沉淀+40min排水，运行周期为10h；最优运行参数为：C／N宜为lO．4， DO宜为2．0 DO宜为2．0 mg／L，MLSS宜为5000 mg／L。优化条件下稳定运行一周期， 总氮去除率可达69．4％，COD去除率为90．1％，氨氮去除率为93．9％，出水 达到畜禽养殖业污染物排放标准GB l 8596．2001。 关键词：猪场废水 微生物活性厌氧消化SBR反应器 生物脱氮 工艺条件优化 Ⅱ EFFECT EFFECT OF AMMoNIA NITROGEN ON ACTIVITY OF ANAERoBIC MICROBE AND BIOLOGICAL NITROGEN REMoVAL IN SCALE PIGGERY WASTE、7I(ATER TREATMENT ABSTRACT Ammonia nitrogen would affect the activity of anaerobic microbe，and谢t11 the synergistic reaction of ammonization,the effect was consolidated in the anaerobic digestion process of scale piggery wastewater．Through anaerobic toxicity assay and sludge activity recovery test,the effect of ammonia nitrogen on activity of anaerobic microbe in simulated wastewater and scale piggery wastewater were studied in this paper．The results showed that the ammonia nitrogen of simulated wastewater affect the methanogenic activity of anaerobic granular sludge，the effect appeared multiplicity．When the ammonia nitrogen concentration Was below 400mg／L，the methanogenic activity Was accelerated．When the ammonia nitrogen concentration Was equal to 800rn#L，the methanogenic activity Was restrained,and谢廿l the ammonia nitrogen concentration rising,the inhibition Was enhanced．The methanogenic activity was restraine