钴基非晶软磁合金的制备与晶化动力学研究-材料学专业论文.docxVIP

Theme Theme of thesis：Study on Preparing and Crystallzation Kinietics of Cobalt-Based Amorphous Alloys Graduate student：Hao Lei Professor：Chen Xue Ding ABSTRACT The Co-based amorphous alloys exhibit excellent soft magnetic properties，such as hi【gh saturation magnetization，large permeability in the high·frequency range，very weak magnetostriction and lOW coercivity and lOSS．They are widely applied in magnetic recording heads．thin film inductors and transforifler cores．The investigation on Co—based amorphous alloys has been the foreland of condensed physics and design to new materials for its unique physical and chemical properties． In this thesis，the Co．based amorphous alloys had been prepared by mechanical alloyin。甙MA)and rapid cooling on a single cooper wheel．The microstructure and the magnetic properties of the composites had been studied and analyzed．The crystallization behavior of the metallic C077．5Sil3．589and C068．5Fe4SiIOBl7．5 were studied by means of transmission electron microscopy(TEM)，differential thermal analysis(DTA)and magnetic measurements． Two modes were used to analysis the crystallization kinetics based on DTA measurements has been performed on the exothermic peaks of the sample．One is non-isothermal crystallization kinetics at constant heating rate．Which Can be analyzed by the Kissinger and Doyle-Ozawa method．The other iS the isothermal crystallization kinetics．which can be discussed in terms of the JMA equation and the Arrhenian relationship． A detailed interpretation of the results lead to some interesting conclusions．The important results we obtamed are as follows： (1)The nine alloys州tll four eutectic compositions and five compound compositions based on the Co—Zr phase diagram formed amorphous alloys．Co and Zr powders can dissolve into each other and the dissolution becomes larger after milling． During the milling process，Zr powders firstly dissolve into the gap of Co crystal 1attice and solid solution with Co supersaturation iS formed．Then．the