含苝酰亚胺聚合物光伏材料的合成与表征-高分子化学与物理专业论文.docxVIP

ABSTRACTPeryleneimides ABSTRACT Peryleneimides have the advantages of thermo stability,exeilence in chemical and optoelectical features．The present thesis tries to combine these characteristics of peryleneimides with the proeessability and flexibility of polymers，aming to get suitable materials for photovoltaic applications． 1：irstly,starting from molecular design，a perylenetetracarboxylic acid bisimides monomer bearing two aldehyde groups(PLCO)was prepared through the functionalization of 3,4，9，10-perylene-tetracarboxylic dianhydride．Another new dianhydride monomer,1．7-bis(N-piperidyl)-perylenetetracarboxylic dianhydride (PePDl Was also synthesized． By using the monomer PLCO，a serie ofperylene-containing polymers，named as PCN，PPOW and PBC，were designed and synthesized through Wittig,Knoevenagel condensations．Another series of perylene-containing polyimides,B12B，B12 and B126F,were synthesized through condensations starting from the monomer PePD． The prepared polymers were characterized by using GPC，FT-IR，UV-vis，TG and CHl650．etc．1H-NMR and Fr．IR proved the successful synthesis of all monorfler8 and polymers．TG analysis revealed that aJl the polymers have excellent thermal stability．Polymers PCN，PPOW and PBC showed strong absorptions in the range of400 nln-600 nul ou their UV-vis spectra,and the band gap ofthese polymers were calculated as about 2．0 eV．WIlile．polymers B12 and B126F have strong absorptions in the range of600／in]-850 rim。and the polymer B12时锄have a broader absorption ranging from 400 anl to 850 nnl which is quite matching with the solar spectrum．The band gap ofpolymers B12B．B12 and B126F were calculated as about 1．50 eV．Cyclic voltammetry analysis illustrated that each of polymers PCN，PPOW and PBC has a stable and reversible redox pair at·O．50 V and the LUMO energy level of these polymers were about-4．20 eV．The stable and reversible redox pair of polymer B126F appeared at一0．55Ⅵand the LUMO energy level Was--4．16 eV． In addition，the prepared polymers sh