甲基丙烯醛一步氧化酯化制甲基丙烯酸甲酯整体式催化剂的制备与研究-化学工艺专业论文.docxVIP

万方数据 万方数据 摘 要 积含量为 35-40%，Al2O3 加入量为 25-30 g/L，沉积电压为 10-12 V，沉积时间为 8-12 min，搅拌速度为 200-250 r/min 时，可制得较佳的涂层。对应的整体式催化 剂上可生成活性中心 Pd3Pb 晶体，且粒径适中，分布均匀。 4）分别将堇青石基和泡沫镍合金基整体式催化剂在固定床反应器中进行了 气-液-固三相反应性能评价，对固定床三相反应制 MMA 的生产新工艺进行了初 步研究。结果表明，整体式催化剂 MAL 转化率最高可达到 76.1%，MMA 选择 性为 81.2%，表明 MAL 氧化酯化整体式催化剂反应性能较好，气-液-固固定床 反应制 MMA 的生产工艺可行。 关键词：甲基丙烯醛 甲基丙烯酸甲酯 堇青石 泡沫镍合金 整体式催化剂 酯化 多相反应 II Abstr Abstract Abstract Methyl methacrylate (MMA), as an important monomer, is widely used in producing acrylic plastics and polymer dispersions for paints, coatings, plexiglass and so on，which can generate polymethyl methacrylate (PMMA) or MMA binary, ternary and quaternary copolymers by homopolymerization or copolymerization. At present, the main commercial process for the production of MMA is the traditional acetone cyanohydrine (ACH) process and the IB oxidation process. The IB oxidation process had attracted more and more attentions for its advantage of highly atom economy, low equipment cost, less side effects and non-corrosiveness.Therefore, many efforts have been devoted to explore this method, especially the reaction of direct oxidative esterification of MAL to MMA. In this dissertation, catalyst and the corresponding fixed bed reaction process of oxidative esterification of MAL with methanol (MeOH) were studied. The main work as follows: The granular catalysts with Pd-Pb compositions using in oxidative esterification of MAL and MeOH were prepared by wet impregnation method and characterizated by different methods,such as BET、XRD、SEM、ICP and TEM，investigated the catalytic performance，the abrasion performance and the Pd-Pb turnover rate of catalyst in stirred tank reactor. The results showed that the lifetime of the catalyst will be reduced because of the catalyst broken and noble metal loss in the long period of agitation process. The MgO-Al2O3 coating on the surface of cordierite was prepared by the method of coating and in situ synthesis. The PdxPby/MgO- Al2O3/ cordierite was prepare