镓（Ⅲ）、锆（Ⅳ）、铜（Ⅱ）络合物在碳糊电极上的吸附伏安法研究-分析化学专业论文.docxVIP

摘 摘 要 本文在查阅大量文献的基础上，提出了在碳糊电极上利用络合 物中配体的氧化、还原峰测定金属离子的新方法。详细研究了镓 (IⅡ)、锆(IⅥ、铜aI)与茜素S(AnS)形成的络合物在碳糊电极上的吸 附伏安行为。 ．一 全文共分三个部分： 第一部分详细研究了镓(m)-AnS络合物在碳糊电极上阴极区 和阳极区的吸附伏安行为，探讨了电极反应机理，研究了电活性络 合物的组成和结构。碳糊电极上的阴极溶出伏安法灵敏度较高，该 方法己成功应用于粮食样品中微量镓的测定。并将其与汞电极上的 吸附伏安行为进行了比较，对两者之间产生差异的原因进行了初步 探讨。 第二部分研究了锆(IV)-ARS络合物在碳糊电极上的阳极吸附 伏安行为。实验发现络合物中的ARS在690mV处产生一灵敏的氧 化峰，二次导数峰高与锆Ⅱv)浓度在1．0x10-9～2．0x101mol／L范围内 呈良好的线性关系，检测限达5．0×10qomol／L(富集2min)。方法成功 地应用于矿石样品中痕量锆的测定。探讨了电极反应机理，确定了 络合物的组成和结构。 第三部分首次提出了利用铜(II)．ARS络合物中的ARS在碳糊 电极上的氧化峰测定铜的新方法。为电活性金属离子的测定提供了 一个新的参考方法。络合物中的ARS在590mV处产生一灵敏的氧 化峰，该峰的二次导数峰高与铜(II)浓度在2．0×lo-9~4．0xlo_7 mol／L 范围内呈线性关系，检出限达8．0×1010mol／L(富集90s)。探讨了电极 反应机理，确定了络合物的组成及其结构。方法已成功的应用于中 草药中微量铜的测定。 总之，本文经过大量实验，提出了灵敏度高，选择性强的测定 镓(III)、锆(Iv)、铜(II)的新方法。 关键词：镓、锆、铜、茜素s、碳糊电极、吸附伏安法 AbstractSeveral Abstract Several new methods were proposed，to determine metal iOIlS Oil the basis of the reduction or oxidization of ligand bonded in complexes at carbon paste electrode．The adsorptive voltammetric behavior of the complexes of Ga(III)-ARS，Zr(W)一ARS and Cu(II)-ARS at carbon paste electrode were studied in detail． There are three parts in this PaDer． In the first part，the adsorptive voltammetric behavior of Ga0II)-ARS complex at a carbon paste eleclrode in cathodic and anodic potential area were studied in detail．111e elec廿ode processes mechanism and the properties of the complex have been investigated．Cathodic adsorptive voltammetry of the system is more sensitive than anodic adsorptive voltammetry and it Was used for the determination of trace gallium in food samples successfully．It also Was compared with the cathodic voltammetric behavior at a mercury electrode．The cause of the difference between the behavior at two kinds of electrodes was discussed primarily． 111 the second part．the anodic adsorptive voltammetric behavior of Zr(IV)-ARS at a carbon paste electrode was studied．There was a sensitive anodic adsorptive peak at 690mV produced by the oxidization of ARS bonded in the complex．The he