煤制乙二醇残液提质的工艺研究-化学工程专业毕业论文.docxVIP

摘要本文为了对具有水、低沸点有机物、易水解酯类及高沸点醇类等特点的煤制L-醇残液进行 摘要 本文为了对具有水、低沸点有机物、易水解酯类及高沸点醇类等特点的煤制L-醇残液进行 综合利用，提出了采用浸没蒸发．活性炭吸附．离子交换树脂吸附法处理后的残液作为生产乙二醇 型防冻液的原料的工艺，对其工艺参数进行研究，获得了乙二醇残液的浸没蒸发、浓缩乙二醇残 液的除味及脱色、浓缩乙二醇残液的脱酸最佳工艺，同时进行概念设计及技术经济初步评价。 1．设计了浸没蒸发装置，优化其实验条件为：气体流量45mL／min、直管浸没深度为液面下 2／3处、蒸发率为62．5％。 2．获得了浓缩乙二醇残液脱色、除味的最佳工艺条件：吸附时间为3h、温度为50℃、振荡 频率为150r／rain、l撑活性炭的投加量为109／50mL浓缩乙二醇残液；在此工艺条件下，浓缩乙二 醇残液无异味，且脱色率为95．48％；另外，活性炭可300℃重复再生使用四次，第四次的脱色率 为92．35％。 3．通过动态吸附试验，筛选D31l树脂为脱酸的吸附剂；优化其预处理时间，确定了分别用 10％NaCl、Imol／LHCl、lmol／LNa0H处理24h的预处理方式；考察了流速对吸附效果的影响， 确定了流速为0．6mL／rain；同时，对树脂再生剂用量进行研究，确定了lmol LNaOH用量为树脂 体积的3倍。 在小试实验的基础上进行了概念设计，包括工艺流程、工艺方案说明、简单的物料和能量衡 算、设备选型等；同时对方案进行了技术经济初步评价，评价结果说明本课题具有经济、社会和 环境效益，可以作为乙二醇残液的资源化再利用方案之一。 关键词；乙二醇残液；提质；浸没蒸发；活性炭吸附；离子交换树脂吸附 万方数据 Abs仃act～1Iling Abs仃act ～1Iling at the comprehensive utilization of raffinate derived from coal-to-glycol，the paper studied the raffinate containing water,a low boiling point organic matter,easy hydrolysis esters and high boiling point alcohols．The raffinate obtained from the combination of submerged evaporation,activated carbon adsorption mad ion exchange resin adsorption methods was applied for producing the raw material of ethylene glycol antifreeze．The investigation of technological parameters acquire the optimum technological conditions for the submerged evaporation of glycol raffinate，enriched glycol raffinate decoloring and taste removal and disacidify of enriched glycol raffinate，carrying out the conceptual design and preliminary evaluation oftechnology and economy． 1．A submerged evaporation device was designed and the optimum operation conditions Was obtained，the results were the gas flow of 45 mL／min,evaporativity of 62．5％and straight pipe of the immersion depth Was located at two-thirds ofthe liquid level． 2．The optimally decoloring and taste-removal technological conditions ofenriched glycol raffinate were determined the following：the adsorption time was 3 h，the temperature WaS 50℃，the oscillation frequency was 1 50 r／rain,mixed the ac