罗汉柏木烯的异构化-化学工程专业毕业论文.docxVIP

摘要甲基柏木蒯是一种重要的单体香料，其中香气的主要载体lsomerG，是由罗 摘要 甲基柏木蒯是一种重要的单体香料，其中香气的主要载体lsomerG，是由罗 汉柏木烯酸催化异构化为OlefinB，然后经过酸催化乙酰化产生的。甲基柏木酮 的品质的高低是由香气决定的，和IsomerG的含量紧密关联。提高IsomerG的得 率将有助于提高甲基柏木酮的品质。 罗汉柏木烯的异构化过程非常复杂，但是主要的反应是沿着两条路径进行 的。主要的反应机理已经彼探明。但是还没有如何提高某一个异构化产物的选 择性的研究。我们的研究主要是寻找一种酸催化剂来应用于罗汉柏木烯的异构 化反应，以期得到多的OlefinB，然后进行乙酰化得到尽可能多的IsomerG。 我们试验了多种固体酸和液体酸，对它们对罗汉柏木烯的催化过程进行了 实验和分析，并对它们的催化选择性进行1r对比。从而挑选出氟硼酸作为选择 性最佳的催化剂进行研究。 通过不同催化剂用量和不同温度下的反应，我们选定了最佳的反应条件。 并且证实了先异构化再进行乙酰化的两步法生产甲基柏木酮能够得到比直接进 行乙酰化的原生产方法更高的lsomerG含量。 我们进一步设计『初步的工艺流程图和工艺操作规程，并对废水处理进行 了初步的规划。使我们的研究成果能较好地应用于生产实践中。 关键词：罗汉柏木烯，酸催化剂，异构化，乙酰化，IsomerG AbstractMCK(Methyl Abstract MCK(Methyl Cedrenyl Ketone)is all important fragrance ingredient，whose main order carrier is IsomerG IsomerG is the product of Acetylation of OlefinB which is from Thujopsene acid—catylized isomerization The qualky of MCK depends on its odor mainly,concerned with the content of IsomerG tightly To improve the containing of IsomerG in MCK will benifit the quality of it welI The isomerization of Thujopsene is very complicated，but the main reactions go along two routes．The mechanisms of those main reactions have been detected But no research has be launched to find a way to get one certain product of isomerization as much as possible．Our research focuses Off looking for an acid—catalyst applied in isomerization of Thujopsene tO get more OlefinB，then to get more IsomerG after acetylation． Many kinds of acids have been studied in our experiments After analysis for their abilities tO the Isomerization of Thujopsene，we compared their catalysis selectivky．then select Fluorid Boric Acid as the best catalyst for farther research The best reaction condition has be ascertained after experiments under various ratioes of catalyst and Thujopsene and temperature It has been approved that the containing of Isomer(3 in the product from the two—step production process is more than the one from the former one—step process We design the elementary process flow chat and the operation