糠醇缩合产物加氢反应规律研究-化学工艺专业毕业论文.docxVIP

万方数据 万方数据 摘要 艺条件下累计非极性产物比例达到 52.9%；二次加氢反应温度升高到 340 ℃， 非极性产物增加到 53.9%。 最后本论文还研究了缩合物以甲苯作为溶剂，使用一次加氢工艺的反应规 律。主要考察了升温方式，反应时间及原料浓度等因素对糠醇缩合物加氢脱氧 反应的影响。发现阶梯升温（温度先升到 260 ℃反应 3 h，接着再升到 340 ℃ 再反应 3 h）的方式有助于更多的非极性物质生成，产物中非极性产物占比为 44.3%。 关键词：生物质；糠醇缩合物；加氢脱氧；烃类燃料 II Abst Abstract Abstract With the dramatic increase in the rapid development of Chinas economy and population,more energy is needed to meet the needs of social development, while there is lack of supply of petroleum resources and the emergence of a global energy crisis, it is very tight to explore complementary and alternative energy oil. As a clean renewable energy biomass is highly concerned to a growing number of countries and research institutions. Literature generally furfural / acetone, 2-methylfuran, levulinic acid is used as raw materials, and through the growth of carbon chains and precious metals hydrodeoxygenation reaction, gasoline, diesel and other biofuels is produced, this paper uses a proprietary biofuel technology roadmap in which furfural alcohol derived from biomass as a raw material, at a certain temperature and sulfuric acid catalysis, through its own chain of condensation achieve the goal, and then get through the catalytic hydrodeoxygenation carbon number C10-C20 hydrocarbons fuel. This paper focuses on the alcohol chain product in a non-precious metal Ni as the main hydrodeoxygenation reaction rule, and accumulate basic research data for the technical route of biomass to generate a new generation of gasoline and diesel by chemical catalytic hydrocarbon fuels. First the composition of furfuryl alcohol chain extension product is studied. By infrared spectroscopy, liquid chromatography methods alcohol condensates were tested and it is found that the condensation product comprises dimers, trimers, tetramers, and a small amount of polymer, the product was dissolved in acetone, ethanol, toluene, but insoluble in water and n-octane. Preliminary hydrogenation and Raney nickel as a catalyst for alcohol con