抗紫外兼具抗菌聚酰胺6纤维的开发-材料工程专业毕业论文.docxVIP

东华大学硕士学位论文抗紫外兼具抗菌聚酰胺 东华大学硕士学位论文 抗紫外兼具抗菌聚酰胺 6 纤维的开发 II II 能添加剂应用母粒法纺制抗紫外兼具抗菌聚酰胺 6 纤维，结果表明（1） Ag 的微量加入对于 TiO2 的晶型无影响；（2）Ag/TiO2 中由于 Ag 可 增加 TiO2 的光活性以及自身可作为电子阱，大幅度提升粉体的紫外 2吸收功能；（3）与 TiO [OSf] 2 相同含量时，含 Ag/TiO2 的纤维可大幅 度提升其抗紫外效果，UPF 值提升 10，抗紫外效果与功能性添加剂 添加量成正相关关系；（4）含[Ag]Ti 粒子的纤维均具有抗菌性，当纤 维中含量达到 2 wt%时，抗菌效果即可达到 99.9%。 关键词：PA6 纤维，表面改性，载银二氧化钛，抗紫外，抗菌 PAGE PAGE IV THE DEVELOPMENT OF UV RESISTANT AND ANTIBACTERIAL POLYAMIDE6 FIBERS ABSTRACT Polyamide6 (PA6) fibers. Due to its high break strength and good abrasion resistance, it is widely used in such as the clothing, carpet decoration and other fields. Especially, PA6 fibers occupy a large market share, and develop very fast in those as underwear, safety belt, parachute, cord fabrics, car-interior textile and et al market. Functional modification particularly multi-functional modification will greatly increased the value and application of general PA6 fibers, and it is also the common and important problem of industry for the moment. Blending method is a common modification method for polymers, which is more suitable for industrial production because of simple operation, low cost and making a range of products by changing the blending ratio. In this paper the UV resistant and antibacterial PA6 fibers were developed by melt blending. [Sf] The different surface modified rutile nanometer TiO2 (TiO2 ) was used as the functional additives in developing the UV resistant and antibacterial PA6 fibers through melt blending. The result as follows (1)The surface modification had no influence on the crystal morphology and the [OSf] UV absorption of TiO2 particles. (2)The organic surface modified rutile nanometer TiO2 (TiO2 ) had the best compatibility and dispersivity with polyamide6.(3)The TiO2[OSf]/PA6 fibers had best [OSf] UV resistance. When the addition is 2wt%, the TiO2 /PA6 fibers can be guaranteed as UV 2resistant, and the UV resistance increased as the addition increased.(4)By only added TiO [Sf] as 2 the functiona