空间高分子材料表面SiO2类薄膜的制备及其原子氧防护分析-材料学专业毕业论文.docxVIP

烟 烟 台 大 学 硕 士 学 位 论 文 IV IV PMMA structure so that the modification not only exist in the surface but penetrate into the substrate which makes it suitable for the high temperature steam condition. Combining the modification of silicone rubber pretreated by high concentration coupling agent (90%), silica films were prepared on the surface of flexible silicone rubber by sol-gel method. The results indicated that the silica sol can easily form a uniform thin film on the surface of silicone rubber compared with the traditional modification by low concentration. The surface morphology of silica film was investigated by scanning electronic microscope (SEM) and shows that the inorganic silica film could combine with organic silicone rubber without obvious delamination on the interface. It proves that the silica film prepared by the base/acid two-step catalytic sol- gel process is nano-porous. In this way the control and adjusting of the transmittance can be realized effectively. The AO resistance performance of SiO2 film prepared on silicone rubber was discussed, and the results showed that for the coated sample, the change of optical transmittance is different from that of uncoated silicon rubber after AO exposure to the fluence of 7.0× 1020 atoms/cm2. It is clearly seen that there is no decrease but actually an increase in the visible spectral region. So the AO exposure could not cause the degradation of optical property of the coating and the film has an effective AO protection. Key words : polymer material; atomic oxygen (AO); SiO2 film; interface modification; sol-gel 烟台大学学位论文原创性声明和使用授权说明 原创性声明 本人郑重声明：所呈交的学位论文，是本人在导师的指导下，独立进行研究工 作所取得的成果。除文中已经注明引用的内容外，本论文不含任何其他个人或集体 已经发表或撰写过的作品或成果。对本文的研究做出重要贡献的个人和集体，均已 在文中以明确方式标明。本声明的法律结果由本人承担。 论文作者签名： 日期： 年 月 日 学位论文使用授权说明 本人完全了解烟台大学关于收集、保存、使用学位论文的规定，即： 按照学校要求提交学位论文的印刷本和电子版本； 学校有权保存学位论文的印刷本和电子版，并提供目录检索与阅览服务； 学校可以采用影印、缩印、数字化或其它复制手段保存论文； 在不以赢利为目的的前提下，学校可以公布论文的部分或全部内容。 （保密论文在解密后遵守此规定） 论文作者签名： 导师签名： 日期： 年 月 日 烟 烟 台 大 学 硕