抗黄变热塑性聚氨酯胶粘剂的制备与性能研究-高分子化学与物理专业毕业论文.docxVIP

摘 要 品、医药等应用领域的危害，本文又探讨了无毒催化剂月桂酸铋的合成及其在聚 氨酯胶粘剂合成中的催化特性。在 90~95℃下，月桂酸经皂化合成月桂酸钠，月 桂酸钠再与硝酸铋经复分解反应，纯化后制得月桂酸铋。加入 0.04%月桂酸铋， 可使一步法合成聚氨酯胶粘剂的反应时间由 4min 降至 2min，表明月桂酸铋具有 明显的催化特性，并在一定程度上提高 TPU 胶粘剂的性能。 关 键 词：抗老化剂，热塑性聚氨酯胶粘剂，合成，性能，月桂酸铋 论文类型：应用基础研究 II 摘 要 Subject: Preparation and Properties of Anti-yellowing Thermoplastic Polyurethane Adhesive Specialty: Polymer Chemistry and Physics Name: Yan Li-min Supervisor: Associate Professor Song Wen-sheng Senior Engineer Zhu Chang-chun ABSTRACT Thermoplastic polyurethane adhesives (TPU) have excellent mechanical, adhesive and resistent low-temperature characteristics, and can be widely applied in many fields. But aromatic TPU are susceptible to aging and degradation in the light for a long time, and the results are that the adhesive strength declines, the adhesive layer yellows and the application effect is not good. In order to improve the anti-aging performance of TPU, except for selecting non-aromatic raw materials, ageing-resistant agents were added to the reaction system for TPU to improve the anti-aging performance of TPU but not to increase the cost of TPU. Thus, the effect of ageing- resistant agents on the technology and properties of TPU was studied in this paper. Moreover, bismuth lauric as a non-toxic catalyst in the application of TPU synthesis was also studied at the same time. In the experiment, TPU were synthesized with poly-butylene adipate glycol (PBA3000), 1,4 - butanediol (BDO), diphenylmethane diisocyanate (MDI) and ageing- resistant agents (UV absorbers, hindered amine light stabilizers, antioxidants) by one- step method. The influences of the following on the properties of TPU were firstly studied. The factors included molecular weight of PBA, BDO addition amount, R value (molar ratio of -NCO/-OH), reaction temperature and post cure conditions. Secondly, the influences of kinds, amount and associative effect of ageing-resistent agents on the mechanical strength and anti-aging performance of TPU w