糠醛气相加氢制糠醇催化剂的研究-工业催化专业毕业论文.docxVIP

中北大学学位论文 中北大学学位论文 中北大学学位论文 中北大学学位论文 I I II II 糠醛气相加氢制糠醇催化剂的研究 摘 要 糠醇是重要的化工原料，糠醇由糠醛加氢制得，可分为液相法和气相法两种方法。 液相法具有能耗高，催化剂分离困难，对设备要求严格等缺点，所以以低能耗的气相法 代替液相法已成为国内外糠醇生产的趋势。 本文以糠醛气相催化加氢制糠醇为研究对象，采用溶胶-凝胶法制备了 CuO/SiO2 负 载型催化剂，探讨了 CuO/SiO2 催化剂的制备条件，如沉淀剂、活性组分负载量、沉淀 pH 值、焙烧温度等对催化剂活性的影响，并利用扫描电子显微镜（SEM）、比表面积 (BET)、X 射线衍射(XRD)、程序升温还原(TPR)和 N2O 表面反应等表征技术手段研究了 制备条件对催化剂结构和物化性能的影响。结果表明，以 Na2CO3 为沉淀剂制备的活性 组分负载量为 30%的 CuO/SiO2 催化剂，在柠檬酸添加量为 5%，沉淀 pH 值为 8.0，焙 烧条件为 450℃焙烧 4 小时的制备条件下，催化剂的活性最好。 在此基础上，又在固定床反应器上考察了最佳反应工艺参数和催化剂的稳定性，结 果表明，在固定床反应器中，常压，反应温度 180℃，氢醛摩尔比为 5，液空速为 1h-1 的条件下，糠醛转化率为 98%以上，糠醇选择性为 99%。连续运行 30h，催化剂开始失 活，将失活的催化剂在空气气氛下 450℃焙烧 4h，可恢复活性，连续使用 20h 后出现明 显失活现象。 关键词：糠醛，气相加氢，糠醇，催化剂 Study on catalysts for vapor phase hydrogenation of furfural to furfuryl alcohol Abstract Furfural alcohol is an important material in the chemical engineering. There are two ways to produce furfuryl alcohol through hydrogenation. One is liquid phase hydrogenation, another is vapor phase hydrogenation. The liquid phase hydrogenation has some disadvantages, such as high energy consumption, difficult separation of catalyst and high requirements for reaction equipment. So it is current that the vapor phase hydrogenation replaces liquid phase hydrogenation of furfural. In this thesis, supported CuO/SiO2 furfural hydrogenation catalysts were prepared by sol-gel method. The effect of the activity and structure of catalysts on different precipitators, CuO contents, pH values and calcination temperatures were characterized by SEM, BET, XRD, TPR and N2O adsorption-desorption. The results showed that Na2CO3 was the suitable precipitator. The best preparation conditions were determined as follow: adding citric acid as cocatalyst, CuO content was 30wt%, citric acid content was 5wt%, pH value was 8.0±0.2, calcination temperature was 450℃ for 4 hours. In these conditions, we can get the best performance of furfural hydrogenation catalyst. The reaction conditions and catalyst stability were also investigated in the fixed-bed r