三元乙丙胶的应用研究-环境科学专业论文.docxVIP

青岛晦洋大学 青岛晦洋大学 硕士论文 三元乙警警用研究摘 要 r≤05997’ 本文主要进行了高硬度耐热三元乙丙胶、低压缩永久变形三元乙 丙胶硫化体系以及改进EPDM胶料高温性能的配方研究。采用电子显微 镜和x射线显微分析仪初步探明了高硫磺获得高硬度的机理。硫磺在 未硫化和硫化胶中的分布存在显著偏差，NR橡胶相在硫化胶中由于显 著的多量硫磺进行交联，成为粒子分散在EPDM中，在两相界面间生成 共交联键，改善了加工性能和实现了高硬度。 (高硬度胶料选用ENB作为第三单体、中碘值和中门尼黏度的EPDM 作为生胶，以次磺酰胺类代替噻唑类由二硫代氨基甲酸盐和秋兰姆活 化，其性能中等。3×O．8体系与Vulcafor2相比性能基本相似，但后 者具有更好的压变性能。 把TMTD确定在高量、低量和中量，对硫磺和cz的变化进行比较， 从而确定了最佳低压变形的不喷霜体系，获得了压变、硫化性能、物 理性能以及焦烧安全性的理想平衡。 通过选用聚合物品种和有针对性的胶料配合，使EPDM的耐高温 长时间老化性能得到根本的改善07 本研究把重点放在对健康和环境无大毒害作用的配合剂选用上， 因而使配方实用有效。 关键词：高硬度橡胶 低压变形 耐热体系 环境保护 —王坠堑量适丛!二——～ —王坠堑量适丛!二——～ 堡主堡塞 The Study of the applications of EPDM Abstract In this paper，high-hardness EPDM being hear resistance．Low compression residual deformation and being used in high temperature were studied．The mechanism of gaining higher—hardness EPDM by using more sulfurs was investigated through SEM and X-ray Microwave Determiner．A notable deviation between cross．1inked rubber and uncross-linked one make NR to disperse in EPDM，and NR became little particles as cross—linking with obviously excessive sulfurs and dispersed in EPDM．At the same time，CO．CROSS bands were formed at the interface of NR，EPDM． EPDM，which has medium Iodine Value and proper Mooney Viscosity with ethidene norbomene as the third monomer，was selected to prepare the product with high—hardness and high heat-resistance．In this formulation，the hypo—sulamine accelerant replaced the thiazole accelerant to improve the scorching and stress-strain properties． Conventional 3x0．8 accelerant system and new type accelerant system of Vulcafor 2 were compared．Both of them were similar at process-ability and cross—linking cycle．However,the product containing Vulcafor 2 had a better compression deformation，especially in a complicated curing system． The curing system when TMTD was set at high，medium，low amount level respectively was evaluated．The amounts of sulfurs and accelerant CZ had effect on the product property．The curing process and t