锂离子电池Li2MnO3基材料的改性及电化学性能研究-新能源材料专业论文.docxVIP

武汉理 武汉理工大学硕士学位论文 万方数据 万方数据 Abstract As power energy of electric vehicle or energy storage device, higher specific discharge capacity and higher rate capacity are required for cathode electrode materials of Li ion batteries. 0.8Li2MnO3·0.2LiCoO2(also named as LMCO) is one of most promising cathode materials of Li ion batteries with higher practical specific discharge capacity (300mAh/g), abundant resource and environmental compatibility. However, the low rate capacity and poor structure stability at high potential (＞4.5V) are the main obstacles for application of LMCO. In this work, electrochemical performance of LMCO is improved by carbon coating and metal doping. The study found that carbon-coating has a higher electronic conductivity, which can improve the rate capacity of LMCO. In this work, LMCO/C cathode materials for Li ion batteries were synthesized by several carbon source, whose rate capacity were studied. Besides, the structure of LMCO was firmed by Nb doping to improve its cycle performance. Carbon source included PVA, sucrose, glucose. The LMCO/C coated by PVA could enhance particles aggregation which is harmful to the electrochemical performance, while the sample coated by glucose could reduce particles aggregation. The sample coated by glucose at 400℃ for 1h showed the best electrochemical performance at current density of 20、50、100 mA/g, respectively; which increased by 10.3, 36.7, 24.5% compared with the sample without carbon coating. LMCO coated by mixture glucose and carbon black had an initial capacity of 256.8, 181.5, 132.4mAh/g at current density of 50,100 ,200mA/g, respectively. Carbon coating can improve the rate capacity, nor for the cycle performance. In this work, the samples of Nb-doped LMCO were prepared by sol-gel-combustion to improve rate capacity and cycle performance. When doping content increase from 1 to 4%, size of sample particle decrease and aggregation reduce; while the size of 5% Nb doped sample increase. The initial capaciti