流化床富氧燃烧试验和成灰特性分析-工程热物理专业论文.docxVIP

哈尔滨工业大学硕士学位论文 哈尔滨工业大学硕士学位论文 II II Abstract With the continuous CO2 emissions, the greenhouse effect and climate change has catched the international communitys attention day by day. Coal-fired power plants are the largest and most concentrated CO2 producers, CCS technology is intended to capture and store CO2 of the power plant flue gas. With the feature of full CO2 capture, low emissions and high economic efficiency, CFB oxy-fuel technology has become a promising technology for CO2 emissions reduction. For the heating surface ash depose seriously of oxy-fuel fluidized bed tail, the article try to start from the fly ash deposition characteristics to examine the circulating fluidized bed combustion of oxygen. This paper selects Jincheng Anthracite and Shuozhou bituminous coal and takes a series of oxygen-enriched combustion experiments on the transformed small-scale fluidized bed. The results show: With the ascendent oxygen concentration of atmosphere, burned coal rise, unit heat of SO2 and NOX emissions increase, the conversion rate of flammable N decline, flammable S first increase and then decreas; the concentration of NOX emissions in the oxygen atmosphere is far below the air atmosphere; sulfur dioxide emissions in air atmosphere is between the amount of 21% -30% oxygen concentration of oxygen enriched atmosphere; As the furnace temperature rise, NOX emissions increase, SO2 emissions increase first then decrease. Using XRD, SEM-EDX to conduct a comprehensive analysis of oxy-fuel fluidized bed’s fly ash, separator ash and bottom ash’s minerals and microcosmic morphology, the results suggest: quartz, hematite, anhydrite, anorthite, metakaolin, mullite, square stone calcium and other minerals are the main mineral phase of enriched combustion fluidized bed’s ash sample; the increase of oxygen concentration in oxygen-rich atmosphere promote the decomposition of Metakaolinite and formation of anorthite. When oxygen concentration rise from 21% to 40%, Metakaolinite pha