离子液体键联壳聚糖衍生物的制备、表征及其催化性能研究-工业催化专业论文.docx

摘要 万方数据 万方数据 应条件为：当 n 苯胺为 5.375 mmol，n 苯胺:n 碳酸乙烯酯:nBPBr group in BPBr-b-CS = 1:4:0.03, 150℃ 反应 6 h 时，催化效果最好，即苯胺的转化率为 91.0％，N-羟烷基化的总产率达 85.1％。并在此最优条件下，对催化反应进行了底物的拓展。 3、1-正丁基-4-吡啶甲醛溴化物离子液体键联壳聚糖衍生物的制备、表征及其催 化性能研究 （1）在水反应介质中，将 1-正丁基-4-吡啶甲醛溴化物离子液体与壳聚糖反 应，生成 1-正丁基-4-吡啶甲醛溴化物离子液体键联壳聚糖衍生物，其取代度为 50.0％。 （ 2 ） 以 1- 正 丁 基 -4- 吡啶 甲 醛 溴 化 物 离 子 液 体 键 联 壳 聚 糖 （ 200 kDa, BFPyBr-b-CS）为催化剂，研究了其对苯胺与碳酸乙烯酯的 N-羟烷基化反应的催 化性能，其最优反应条件为：当 n 苯胺为 5.375 mmol，n 苯胺:n 碳酸乙烯酯:nBFPyBr group in BFPyBr-b-CS = 1:4:0.06, 150℃反应 5 h 时，催化效果最好，即苯胺的转化率为 74.2％， N-羟烷基化的总产率达 74.2％。并在此最优条件下，对催化反应进行了底物的 拓展。 4、离子液体键联壳聚糖衍生物催化剂催化芳烃和碳酸乙烯酯进行 N-羟烷基化反 应时，当芳香胺中带有给电子取代基时，会使其转化率提高；当芳香胺中带有 吸电子取代基时，会使其转化率降低。 关键词：壳聚糖；键联；离子液体；制备；催化；N-羟烷基化反应 II Abstract Abstract Using chitosan as raw material, the ionic liquids bonded on chitosan derivatives (IL-b-CS) were synthesized by the reaction of ionic liquids with chitosan. The catalytic performance of IL-b-CS on the N-hydroxyl alkylation reaction of aromatic amine and ethylene carbonate was studied. The study not only provides a new idea and method for the modification of chitosan, but also provides a new type catalyst for N-hydroxy alkylation reaction of aromatic amine with ethylene carbonate. So the study has some academic significance and potential application value. Preparation, characterization and catalytic performance of methyl imidazole bromide bonded on chitosan derivatives Methyl imidazole bromide bonded on chitosan (10 kDa) was synthesized in isopropyl alcohol-water system. The results showed that the degree of substitution of 3-(4-bromobutane)-1-methyl imidazolium bromide bonded on chitosan (BBMIB-b-CS) is the highest and arrives at 38.2%. 3-(4-Bromobutane)-1-methyl imidazolium bromide bonded on chitosan (10 kDa ) was synthesized in both isopropyl alcohol-water and water system, respectively. The results show that the degree of substitution in the water system is higher than in the isopropyl alcohol-water system, and arrives at 45.7%. 3-(4-Bromobutane)-1-