EGR率对LNT吸附路径及净化效果的影响研究.docVIP

基金项目：国家自然科学基金；清华大学汽车安全与节能国家重点实验室开放基金 (KF1818）；移动源污染排放控制技术国家工程实验室开放基金资助项目（NELMS2017A02） 中国工程热物理学会 燃烧学 学术会议论文 编号：184137 EGR率对LNT吸附路径及净化效果的影响研究 李志军1，曹丽娟1，申博玺1，朱伶雅1，吴越1，李世龙1 （1.天津大学内燃机燃烧学国家重点实验室，天津 300072） (Tel Email:zhijunli@tju.edu.cn) 摘 要 本文建立了包含两种吸附路径的LNT模型，研究了不同EGR率对吸附路径及NOx净化效果的影响，得到以下结论：EGR对硝酸盐和亚硝酸盐路径均有影响。0%~15%EGR率内，EGR对硝酸盐路径的抑制作用和对亚硝酸盐路径的促进作用均随EGR率增加而加强。20%~30%EGR率内，EGR对两种路径均表现为抑制作用，且抑制作用随EGR率增加变化微弱。0%EGR率时硝酸盐和亚硝酸盐路径储存比值约为1:1.75，25%EGR率时储存比值约为1:2.85。不同EGR率范围内NOx转化率变化趋势有差异。 关键词 稀燃氮氧催化器；EGR率；硝酸盐；亚硝酸盐；吸附路径 Study on Effect of EGR Rate on Adsorption Path and Purification Effect Li Zhijun1, Cao Lijuan 1, Shen Boxi1, Zhu Lingya1, Wu Yue1, Li Shilong1 (1. State Key Laboratory of Engines, Tianjin University, Tianjin China, 300072) Abstract: Lean NOx Trap (LNT) model is developed, it contains both two adsorption paths, the influence of different EGR rates on the adsorption path and NOx purification effect are investigated. The following conclusions are drawn. EGR has influence on both nitrite and nitrate paths. At EGR rate of 0%~15%, the degree of inhibition effect on nitrate path and improvement on nitrite path both increase as EGR rate increases. While in the range of 20%~30%, EGR has inhibition effect on two paths, and influence degree changes slightly with EGR rate increasing. Under 0% EGR rate, adsorption ratio through the nitrate path and the nitrite path is approximately 1:1.75, while the ratio is approximately 1:2.85 under 25% EGR rate. NOx conversion behaves different trend at different EGR rates. Keywords: Lean NOx Trap; EGR Rate; nitrate; nitrite; adsorption path 0 前言 LNT在发动机稀浓燃交替变换下实现NOx的吸附还原,在稀燃氛围中涂覆在Al2O3载体上的碱及碱土金属氧化物如K或Ba吸附NOx形成硝酸盐或亚硝酸盐进行储存，在浓燃氛围中排气中的还原性气体如HC、CO等将脱附出的NOx还原为N2，使催化器能够及时释放有效吸附位，参与下一循环的吸附过程[1-2]。近年来LNT内部氮氧化物的储存始终是研究重点，学者们已构建部分储存机理[3-5]，但尚未形成统一定论。大致可将NOx在LNT中的储存归结为两个并行的路径：其一硝酸盐路径，即NOx首先在贵金属表