Ni-Fe橄榄石催化剂循环流化床催化气化实验研究.docxVIP

中国工程热物理学会 燃烧学 学术会议论文 编号：184209 Ni-Fe橄榄石催化剂循环流化床催化气化实验研究 孟俊光1,2，王小波基金项目：国家自然科学基金，广东省科技攻关计划(2015A020215023)，赵增立1,* 基金项目：国家自然科学基金，广东省科技攻关计划(2015A020215023) ( 1．中国科学院广州能源研究所 中国科学院可再生能源重点实验室， 广东 广州510640; 2.中国科学院大学， 北京100049) Tel：020Email：mengjg@ms.giec.ac.cn 摘要：在3-5kg/h的生物质循环流化床中，采用浸渍法和热熔融法制备的Ni-Fe橄榄石催化剂作为床料，结合一系列催化剂表征手段，考察了不同的反应温度，当量比，固体循环率以及不同橄榄石催化剂对生物质催化气化气体组分及焦油含量的影响。结果表明，raw-olivine相比于石英砂为床料时，焦油含量降低了38.0%。煅烧之后由于橄榄石内部Fe向表面迁移，催化能力进一步提高，焦油含量(1100-olivine)相比于raw-olivine又降低了55.9%。采用浸渍法和热熔融法制备的橄榄石催化剂由于Fe2O3，NiO-MgO，NiFe2O4活性中心的形成，进一步提升了焦油裂解能力，1100-WI-olivine和1400-TF-olivine相比于 1100-olivne对焦油裂解率又分别提升了58.1%和61.1%。 关键词：橄榄石，循环流化床，焦油，催化气化 Comparing study of Ni-Fe olivine catalysts prepared by different methods in circulating fluidized bed gasification Junguang Meng1,2, Xiaobo Wang1, Zengli Zhao1，*, Anqing Zheng1, Zhen Huang1, Guoqiang Wei1, Haibin Li1 ( 1.The Key Laboratory of Renewable Energy of Chinese Academy of Sciences， Guangzhou Institute of Energy Conversion, Chinese Academy of Sciences, Guangzhou 510640, China; 2. University of Chinese Academy of Sciences, Beijing 100049, China) Abstract: Ni-Fe olivine catalysts synthesized using thermal fusion (TF) and wetness impregnation methods as bed materials were investigated in a circulating fluidized bed for biomass gasification. The effects of reaction temperature, equivalence ratio (ER) and solid circulation rate on syngas products and tar content were examined. The physiochemical properties of catalyst were analyzed, which contain structure presentation: X-Ray diffraction (XRD), temperature program reduction (TPR); surface measurements: BET surface area, scanning electron microscopy (SEM) and X-ray photoelectron spectroscopy (XPS). The results showed that the raw-olivine as bed material had good tar catalytic cracking ability, and the tar content was reduced by 38.0% compared with the