炭化活化两步法与一步法制备粉焦的实验研究.docxVIP

中国工程热物理学会 燃烧学 学术会议论文 编号：184440 炭化/活化两步法与一步法制备粉焦 的实验研究 周滨选，王涛，徐天明，刘志，马春元 （山东大学 燃煤污染物减排国家工程实验室，山东 济南 250061） （Tel Email： zbx_4023@163.com） 摘 要 以蒙东褐煤为原料，以模拟燃煤热烟气为热源和介质，在一维沉降炉上分别进行先炭化、后活化（两步法）及同时炭化、活化（一步法）制备粉状活性焦的实验研究。结果表明，一步法制备粉焦的收率要高于两步法，而在孔隙结构参数、SO2吸附硫容方面，两步法制备的粉焦与一步法相差无几；按基于单位质量原料的硫容分析，一步法制备粉焦的总体效果略低于两步法，但是，一步法的最大优势在于大大简化工艺，投资、运行成本大幅降低。 关键词 粉状活性焦；制备；一步法；两步法 Experimental Study on Preparation of Powder Coke Using Two-Step Method and One-Step Method about Carbonization and Activation Zhou Binxuan, Wang Tao, Xu Tianming, Liu Zhi, Ma Chunyuan (National Engineering Laboratory of Coal-Fired Pollution Reduction,Shandong University,Jinan 250061,China) （Tel Email： zbx_4023@163.com） Abstract: Mengdong lignite was used to prepare activated coke under the condition of coal-fired hot gas in a drop-tube reactor. Two different methods were used in this study: the two-step method of separating carbonization and activation, and the one-step method of coupling carbonization and activation. The results indicate that the powder coke yield of one-step method is slightly higher than that of the two-step method, and in the aspect of pore structure parameters and SO2 adsorption sulfur content, the powder coke prepared by two-step method is similar to that of one-step method. According to the sulfur capacity analysis based on unit quality raw materials, the two-step method is significantly better than the one-step method about the effect of 基金项目：国家重点研发计划 （2017YFB0602902） preparation, but the biggest advantage of one-step method is to greatly simplify the process, and the investment and operation costs are greatly reduced. Keywords: powdered activated coke; preparation; one-step method; two-step method 0 前言 燃煤锅炉烟气排放的 SO2 ，是造成酸雨等大气污染的主要来源，为了控制 SO2 的排放，烟气脱硫技术便得到了大量推广及广泛应用。目前，在各种烟气脱硫技术中，石灰石/石膏湿法烟气脱硫技术比较成熟，应用最广，但其存在耗水量大、脱硫副产物大量堆积等问题而引发环境二次