高等有机化学教案3反应机理概述.pptVIP

Mechanism The order of events in going from reactant to product. An “event” is a breaking of a bond, the making of a bond, or the simultaneous making and breaking of a bond. Hammond’s Postulate If two states, as for example, a transition state(TS) and an unstable intermediate, occur consecutively during a reaction process and have nearly the same energy content, their interconversion will involve only a small reorganization of the molecular structures. * *