微孔_介孔复合分子筛的合成及其对co_2的吸附性能.doc

March [Article]物理化学学报(WuliHuaxueXuebao)ActaPhys.-Chim.Sin.2011,27(3),689-696689 微孔/介孔复合分子筛的合成及其对CO2的吸附性能 马燕辉赵会玲唐圣杰胡军*刘洪来 (华东理工大学教育部先进材料及其制备重点实验室,化学系,上海200237) 摘要:采用两步晶化法将合成的沸石前驱液(S)或沸石固体粉末(P)经不同浓度(c)的NaOH处理后,分别以表 面活性剂十六烷基三甲基溴化铵(CTAB)软模板或介孔炭(Meso-C)硬模板为导向剂,自组装合成S-β-MCM41(c)、P-β-MCM41(c)、P-ZSM-MCM41(c)、P-ZSM-C系列微孔/介孔复合分子筛.考察了沸石分子筛种类、碱处理液 浓度以及介孔模板剂对合成复合分子筛结构与性能的影响.X射线衍射(XRD)、透射电子显微镜(TEM)和氮气 吸附-脱附表征结果表明产物具有微孔/介孔多级孔结构.该材料对CO2的吸附能力比纯微孔或介孔材料均有明 显提高,其中P-ZSM-MCM41(2)的CO2吸附容量最大可达1.51mmol·g-1,为ZSM-5沸石吸附量的两倍多. 关键词:微孔/介孔复合分子筛;二氧化碳吸附;双模板;两步晶化;碱浓度 O647中图分类号: SynthesisofMicro/MesoporousCompositesand TheirApplicationasCO2Adsorbents MAYan-HuiZHAOHui-LingTANGSheng-JieHUJun*LIUHong-Lai (LaboratoryforAdvancedMaterialsοfMinistryofEducation,DepartmentofChemistry,EastChinaUniversityofScienceand Technology,Shanghai200237,P.R.China) Abstract:Wesynthesizedaseriesofmicro/mesoporouscompositesofS-β-MCM41(c),P-β-MCM41(c), P-ZSM-MCM41(c),P-ZSM-Cthroughatwo-stepcrystallizationprocess.Duringthisprocess,the microporouszeoliteprecursorsolution(S)orthezeolitepowder(P)wasfirstsynthesizedandtreatedwithNaOH solutionwithdifferentconcentration(c),andthenthemesoporeswereinducedbyhexadecyltrimethyl- ammoniumbromide(CTAB)asasofttemplateormesoporouscarbonasahardtemplate.Theeffectsofthe typeofinorganicprecursor,thebaseconcentration,andthetypeofmesoporoustemplateonthestructure andpropertyofthemicro/mesoporouscompositeswereinvestigated.TheresultsofX-raydiffraction (XRD),transmissionelectronmicroscopy(TEM),andnitrogenadsorption-desorptionisothermsshowed thattheproductscontainedmicroporesandmesopores,simultaneously.TheCO2adsorptioncapacitiesof thesemicro/mesoporouscompositeswereobviouslyimprovedcomparedtothepuremicroporousor mesoporousmaterials.Amongthem,P-ZSM-MCM41(2)hadthehighestCO2adsorptioncapacityof1.51 mmol·g-1,whichwasalmosttwicethatoftheoriginalZSM-5. KeyWords:Micro/mesoporouscompositematerial; crystallization;CO2adsorption;Dual-template;Two-step BasicsolutionconcentrationReceived:September21,2010;Revised:De