基于聚苯并咪唑的新型中高温质子交换膜的制备和性能表征.docxVIP

基于聚苯并咪哩的新型中高温质子交换膜的制备和性能表征 摘要 质子交换膜材料近期由于成本贵和不耐用的问题而饱受争议。成功的主要障碍在于需要解决高温PEM的一系列商业化燃料电池性质。在学者们辛苦研究下，质子交换膜得到了很多改善。我们课题组致力于探究一种新的聚合物膜结构，以适应科技研究对质子交换膜的日益增长的需求。 为了使膜材料质子的传导性能得到强化，保证掺杂了磷酸后物理性能合格，增强氧化稳定性，提高掺杂的性质，减少相关的损失，本文将制备的几种低聚物片段和单体，分别对于低聚物和单体的性质进行了表征后又合成目标共聚物并进行相关性质得表征。通过调整低聚物组成的部分以合成不同型的聚合物质，对比性质做出最优的选择，以实现实验的设想，使质子的交换膜的相关应用能够再进一步地完善和可以进一步拓展。 测试结果表明，聚合物的质子传导率和抗氧化能力得到了增强，也在一定程度上减少了磷酸掺杂后的丢失。 关键词：聚合反应，苯并咪哩，质子交换膜。 Preparation and properties on the new type ofpolybenzimidazole characterization of proton exchangemembrane of high temperature Abstract Inadequate performance, short term durability and high cost of polymer electrolytemembrane (PEM) are the major roadblocks that need to be resolved for successfulcommercialization of high temperature PEM fuel cell. Through the tireless efforts ofscientists, technology has made considerable development of proton exchange membrane.Our team is committed to explore a new kind of polymer membrane structure, to adapt tothe technology research of the growing demand for proton exchange membrane. In order to improve the proton conductivity of proton exchange membrane, enhance themechanical properties after the doped phosphate, enhance the antioxidant capacity, improvethe level of doping, reduce the loss, in this paper, the preparation of several segments ofoligomer and monomers, the nature of oligomer and monomers were characterizedrespectively after synthesis target and the properties of the copolymer characterization. Byadjusting the oligomer components in synthesis of different polymers, comparing propertiesto make the best choice, in order to realize the experimental idea, make relevant applicationof proton exchange membrane can further develop. Test results show that the proton conductivity of polymer and antioxidant ability has beenenhanced, also to a certain extent, reduce the loss of the doped phosphate. Key words: Polymerization, benzene and imidazole, proton exchangemembrane. TOC \o 1-5 \h \z .、八 刖言 5