零动能光电子能谱.pptVIP

Zero Kinetic Energy Photoelectron Spectroscopy Contents ZEKE spectroscopy Applications Prospects Background 1 2 3 4 ZEKE PES TPES MATI Photoelectron spectroscopy Threshold photoelectron spectroscopy Zero kinetic energy spectroscopy Mass-analyzed threshold ionization spectroscopy 1. Background Principle Photoelectron spectroscopy (PES) Key requirement results measure the electron kinetic energy, limits the working resolution to about 80cm-1. Ionization potential of molecule , electronic, vibrational states in the molecular ion. irradiation by light of a specific wavelength, energy conservation In the 1960s, Turner et al., Terenin et al., and Siegbahn et al. Supersonic jet cooling: reduces the number of populated states, avoids congestion, enhances resolution only marginally. Laser multiphoton ionization (MPI) methods: a resonant intermediate state and the high resolution of tunable lasers,obtains added selectivity and sensitivity. This resolution is not allow observation of the rotational level structure of molecular ions. Al-Joboury, M. I.; Tuner, D. W. J. Chem. Soc., Part 5, 5141-5160 (1963). Terenin, A.; Vilessor, F. Adv. Photochem., 2, 385-400 (1964). Siegbahn, K. Rev. Mod. Phys., 54, 709-741 (1982). Threshold photoelectron spectroscopy (TPES) TPES techniques produces electrons from just above the ionic eigenstates. The spectrum is obtained by collecting threshold photoelectrons (those with little or no kinetic energy) that are produced as a tuneable source of ionization radiation is scanned across each ionization threshold. The resolution is limited by the bandwidth of the radiation. Kinetic electrons from autoionization or directly ionization. 25cm-1 TPES PES 2. ZEKE spectroscopy If the photon energy exactly