基于小麦秸秆纤维素的互穿聚合物的制备.pdfVIP

基于小麦秸秆纤维素的互穿聚合物的制备 摘 要 通过溶液聚合制备了一种基于小麦秸秆纤维素-g-聚丙烯酸网络 WSC-g-PAA）和 线性聚乙烯醇 PVA）的互穿聚合物网络 IPNs），并将该超吸水性树脂 SAR）与尿素和磷酸 氢二钾复合得到高吸水缓释肥料 WSC-g-PAA/PVA/NP）。利用红外光谱 FTIR）、电镜 SEM）、热重 TGA）对 IPNs SAR 进行表征，研究了不同条件下的吸水性和 WSC-g PAA/PVA/NP 的缓释性能。在优化条件下合成的 IPNs SAR 不仅在蒸馏水中表现出 198.5g/g 的 优异的吸水性、在质量分数为 0.9%NaCl 溶液中表现出 26.3g/g 的优异的吸水性，也可以显著减 少肥料的浸出损失并提高土壤的保水能力。试验结果表明：WSC-g-PAA/PVA/NP 具有吸水缓释 性能，在农业和园艺中具有很大的潜力。 关键字 麦秸；IPN；缓慢释放；吸水性；肥料 Preparation of Interpenetrating Polymers Based on Wheat Straw Cellulose Abstract A interpenetrating polymer network (IPNs) found on wheat straw cellulose-g-polyacrylic acid network (WSC-g-PAA) and linear polyvinyl alcohol (PVA) was prepared by solution aggregation，and then Urea and dipotassium hydrogen phosphate were combined with superabsorbent resin (SAR) to obtain the slow release fertilizer with superabsorbent (WSC-g-PAA/PVA/NP). The new IPNs SAR was characterized by FTIR, SEM and TGA. The water absorption in diverse case and the sustained - release properties of WSC-g-PAA/PVA/NP were studied. The semi-IPNs SAR synthesized under optimized conditions exhibited excellent water absorption of 198.5 g/g in distilled water and exhibited excellent water absorption of 26.3 g/g in 0.9% NaCl solution, in addition significantly reduced Fertilizer loss and improved soil water retention capacity. From this experiment, we can conclude that products with sustained- release performance are good for the environment and have great potential in agriculture and horticulture. Keywords： Wheat straw ；IPNs；Slow release；Water absorbency ；Fertilizer 前 言 肥料和水对现代农业生产起着重要作用，因此提高水资源和肥料养分的利用率是非常重要 的。导致全球气候改变的最主要的问题之一是干旱，土壤退化是限制中国农业可持续进展的重要