温度溶剂双梯度高效液相色谱法测定环境空气中的实验分析（农林学论文资料）.docVIP

温度溶剂双梯度高效液相色谱法测定环境空气中的实验分析（农林学论文资料） 文档信息 ： 文档作为关于“行业资料”中“化学工业”的参考范文，为解决如何写好实用应用文、正确编写文案格式、内容素材摘取等相关工作提供支持。正文7164字，doc格式，可编辑。质优实惠，欢迎下载！ 目录 TOC \o 1-9 \h \z \u 目录 1 正文 1 文1：温度溶剂双梯度高效液相色谱法测定环境空气中的实验分析 2 1 材料与方法 4 2 结果与分析 5 3 结论 7 文2：高分辨气质联用法测定环境空气中的12种多氯联苯类化合物 7 1 前言 7 3 结果与分析 9 4 结论 10 参考文摘引言： 10 原创性声明（模板） 11 文章致谢（模板） 11 正文 温度溶剂双梯度高效液相色谱法测定环境空气中的实验分析（农林学论文资料） 文1：温度溶剂双梯度高效液相色谱法测定环境空气中的实验分析 Determination of Carbonyl Compounds in Ambient Air by Temperatureolvent Double-Gradient High Performance Liquid Chromatography Wang Fei et al. （Shaanxi Environmental Monitoring Center，Xi′an 710054，China） Abstract：A seitive method based on derivatization with 2，4-dinitrophenylhydrazine（DNPH）followed by temperature/organic solvent double-gradient high performance liquid chromatography analysis of 13 carbonyl compounds（6 aliphatic，2 aromatic and 3 uaturated aldehydes and 2 ketones）in ambient air was conditio including chromatographic column，column temperature，and detection wavelength were investigated so that the separation was carried out on gradient elution using two solvents（water and acetonitrile）. The problem that the C3 series（acrolein-DNPH，acetone-DNPH and propionaldehyde-DNPH）and C3 series（crotonaldehyde-DNPH，methacrolein-DNPH，2-butanone-DNPH and butyraldehyde-DNPH）in 13 carbonyl compounds were difficlut to separate were solved using temperature optimized method has been validated when rectilinear relatiohip was obtained between the concentratio of analytes and peak area，and the correlation coefficients were ≥ 9. The limits of detection for air samples of L varied between ～μg/m3 expressed as method relative standard deviatio（%D）of all applied carbonyls were lower than %，and spiked recoveries were in the range of 95%～106%. The method was applied to monitor the concentration of carbonyl compounds in ambient air. Key words：Carbonyl compounds；Ambient air；2，4-dinitrophenylhydrazine；Temperatureolvent double-gradient；Liquid chromatography 羰基化合物