硒酸泥制备粗硒新工艺.docxVIP

硒酸泥制备粗硒新工艺 李倩;张宝伸文前;杨兴文 【摘要】 Crude selenium was prepared from selenium acid mud using a new technology of kerosene desulphurization, oxidization-leaching and reduction-extraction of selenium. The results show that kerosene can effectively remove sulfur from selenium acid mud when the temperature is controlled above 95°C, and the rate of desulphurization is larger than 97%. Accordingly, the optimum oxidization-leaching conditions are determined as follows: temperature 80C, leaching time 2 h and ratio of liquid to solid of 5:1, H2SO4 concentration 300 g/L. After oxidization-leaching under optimu