荧光增白剂28的光漂白特性研究.docVIP

  荧光增白剂 28 的光漂白特性研究# 巩宗爱，胡柏，沈晓芳，庞月红** （江南大学食品学院，江苏 无锡 214122） 5 10 15 20 25 30 摘要：荧光增白剂 28(F-28)为欧盟标准 EN 648-2006《与食品接触的纸和纸板-荧光增白剂牢 度的测定》中判断食品接触材料中荧光增白剂是否向食品中迁移的标样。我们研究发现，在 规定的 365 nm 紫外激发下，F-28 所制成的标样会出现光漂白现象。因此，本文对 F-28 光漂 白特性进行研究。结果发现：紫外辐照时间为 60 s 时，四级（3 mg/L）、三级（8 mg/L）、 二级（31 mg/L）、一级（125 mg/L）的滤纸和玻纤最大荧光值衰减率分别为 0.16%、0.29%、 0.92%、0.44%和 2.59%、1.99%、0.49%、3.14%；当辐照时间延长到 1800 s 时，最大荧光值 衰减率分别增加为 4.67%、4.22%、5.51%、2.75%和 35.37%、39.78%、28.09%、39.38%。 因此，在对食品接触材料是否含有荧光增白剂以及是否迁移测试中，必须考虑光漂白因素。 同时，滤纸作为迁移实验载体，在降低光漂白和稳定性方面比玻纤更具优势。 关键词：荧光增白剂；食品接触材料；光漂白 中图分类号：TS77 Photobleaching Rules of Fluorescent Brightener 28 GONG Zongai, HU Bo, SHEN Xiaofang, PANG Yuehong (School of Food Science and Technology, Jiangnan University, JiangSu WuXi 214122) Abstract: The Fluorescent Brightener 28 (F-28) is used as a standard fluorescent whitening agent to conform the migration of fluorescent brightener from the contact materials to food in the European Union Standards EN 648-2006“Paper and board intended to come into contact with foodstuffs determination of the fastness of fluorescent whitened paper and board”. However, to date the effect of fluorescent photobleaching of F-28 has not been studied. The filter paper and glass fiber paper stained by F-28 were evaluated as fluorescent whitened comparison papers and the excitation wavelength was set at 365 nm. The results showed that the attenuation rate with excitation time of 60 s of Evaluation Grade 4 (3 mg/L), Evaluation Grade 3(8 mg/L), Evaluation Grade 2 (31 mg/L), Evaluation Grade 1 (125 mg/L) on filter paper and glass fiber paper were 0.16%, 0.29%, 0.92%, 0.44%, 2.59%, 1.99%, 0.49% and 3.14%, respectively. Moreover, the attenuation rate increased to 4.67%, 4.22%, 5.51%, 2.75%, 35.37%, 39.78%, 28.09% and 39.38% when 1800 s irradiated. Therefore, specify procedures should be considered in the testing of the fastness of fluorescent whitened paper to come into contact with foodstuffs. And the fluorescence of filter paper is more stable